Ag/Zn Galvanic Couple Cotton Nonwovens with Breath-Activated Electroactivity: A Possible Antibacterial Layer for Personal Protective Face Masks

The water vapor exhaled by the human body can severely accelerate the charge dissipation of commercial face masks, thereby reducing the electrostatic adsorption efficiency and increasing the bacterial invasion risk. This study developed an electroactive antibacterial cotton nonwoven (Ag/cotton/Zn) using eco-friendly magnetron sputtering technology. The Ag/Zn electrode constructed on the surface of cotton nonwovens could produce a microelectric field in the moist environment of human respiration, which endowed Ag/cotton/Zn with excellent electroactivity. When Ag/cotton/Zn was used as an additional layer of polypropylene melt-blown nonwovens or polylactic acid nanofibers, the prepared personal protective air filter had a filtration efficiency of up to 96.8% and an appropriate pressure drop and air permeability. The antibacterial results based on bacterial aerosols showed that the antibacterial efficiency against Escherichia coli and Staphylococcus aureus in 20 min was 99.74 and 99.79%, respectively, indicating an excellent electroactive killing efficiency against airborne bacteria. In addition, Ag/cotton/Zn showed excellent biological security. These results shed some light on the design and fabrication of next generation of personal protective air filter materials driven by human breathing.