journal article·2019-07-03

Deciphering Erasing/Writing/Reading of Near-Infrared Fluorophore for Nonvolatile Optical Memory

Nuo-Hua Xie, Cheng Fan, Huan Ye, Kai Xiong, Chong Li, Ming-Qiang Zhu

ACS Applied Materials & Interfaces· Volume 11· Issue 26
Publisher page

Abstract

A near-infrared fluorescence-switchable molecule, dithienylethene-terrylenediimide (TDI-4DTE) exhibits high near-infrared fluorescence and on/off ratio, decent reversibility, and fatigue resistance upon alternating UV/vis (305/621 nm) irradiation. Photoinduced electron transfer mainly contributes to the fluorescence quenching of TDI-4DTE. As an information storage unit, single molecular TDI-4DTE in the polymer film can be written by red light (621 nm) and erased by UV light (305 nm), while nondestructive fluorescence readout (750 nm) of a single molecular memory has been obtained upon excitation with near-infrared light (720 nm). The fluorescence patterning of TDI-4DTE in the polymer film demonstrates that the erasing/writing/reading wavelengths are deciphered to minimize the signal crosstalk in nonvolatile fluorescent molecular memories.
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Research context

OpenAlex topics: Photochromic and Fluorescence Chemistry · Photoreceptor and optogenetics research · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China

Funding

Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · Natural Science Foundation of Hubei Province · National Natural Science Foundation of China

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