Light-Controlled Reversible Release and Uptake of Potassium Ions from Ion-Exchanging Nanospheres

Here, we report for the first time on photoswitchable nanospheres containing spiropyran (Sp) for reversible release and uptake of metal ions. K(+) is used as a model ion to demonstrate the chemical principle of this approach. Valinomycin is incorporated in the nanospheres to stabilize K(+). Upon UV illumination, Sp transforms to the more basic ring-opened merocyanine form, which takes up H(+) from the surrounding aqueous solution and expels K(+) from the nanospheres. The process can be reversed by irradiation with visible light to reduce the surrounding K(+) concentration.