journal article·2023-01-25Open access

Thermal Recovery of the Electrochemically Degraded LiCoO2/Li7La3Zr2O12:Al,Ta Interface in an All-Solid-State Lithium Battery

Martin Ihrig, Liang-Yin Kuo, Sandra Lobe, Alexander M. Laptev, Che-an Lin, Chia-hao Tu, Ruijie Ye, Payam Kaghazchi, Luca Cressa, Santhana Eswara, Shih-kang Lin, Olivier Guillon, Dina Fattakhova-Rohlfing, Martin Finsterbusch

Abstract

High Resolution Image Download MS PowerPoint Slide All-solid-state lithium batteries are promising candidates for next-generation energy storage systems. Their performance critically depends on the capacity and cycling stability of the cathodic layer. Cells with a garnet Li 7 La 3 Zr 2 O 12 (LLZO) electrolyte can show high areal storage capacity. However, they commonly suffer from performance degradation during cycling. For fully inorganic cells based on LiCoO 2 (LCO) as cathode active material and LLZO, the electrochemically induced interface amorphization has been identified as an origin of the performance degradation. This study shows that the amorphized interface can be recrystallized by thermal recovery (annealing) with nearly full restoration of the cell performance. The structural and chemical changes at the LCO/LLZO heterointerface associated with degradation and recovery were analyzed in detail and justified by thermodynamic modeling. Based on this comprehensive understanding, this work demonstrates a facile way to recover more than 80% of the initial storage capacity through a thermal recovery (annealing) step. The thermal recovery can be potentially used for cost-efficient recycling of ceramic all-solid-state batteries.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Energy and Climate Research − Materials Synthesis and Processing, Forschungszentrum Jülich GmbH, 52425Jülich, Germany

Department of Chemical Engineering, Ming Chi University of Technology, No. 84, Gungjuan Road, New Taipei City24301, Taiwan

Łukasiewicz Research Network − Poznan Institute of Technology, 6 Ewarysta Estkowskiego St., 61-755Poznań, Poland

Department of Materials Science and Engineering, National Cheng Kung University, No. 1, University Road, Tainan City701, Taiwan

Hierarchical Green-Energy Materials Research Center, National Cheng Kung University, No. 1, University Road, Tainan City701, Taiwan

MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, Enschede7500AE, The Netherlands

Luxembourg Institute of Science and Technology, Advanced Instrumentation for Nano-Analytics (AINA), rue du Brill 41, 4422Belvaux, Luxembourg

Program on Smart and Sustainable Manufacturing, Academy of Innovative Semiconductor and Sustainable Manufacturing, National Cheng Kung University, Tainan City701, Taiwan

Jülich-Aachen Research Alliance: JARA-ENERGY, 52425Jülich, Germany

Faculty of Engineering and Center for Nanointegration Duisburg-Essen, University Duisburg-Essen, Lotharstr. 1, 47057Duisburg, Germany

Funding

Bundesministerium f?r Bildung und Forschung · Fonds National de la Recherche Luxembourg · National Science and Technology Council (NSTC), Taiwan

References (53)

Show source-provided references
1. 10.1016/j.joule.2019.02.00610.1016/j.joule.2019.02.006 ↗
2. 10.1002/aenm.20200131810.1002/aenm.202001318 ↗
3. 10.1021/acs.chemrev.9b0042710.1021/acs.chemrev.9b00427 ↗
4. 10.1016/j.joule.2019.03.01910.1016/j.joule.2019.03.019 ↗
5. 10.1021/acsaem.1c0266710.1021/acsaem.1c02667 ↗
6. 10.1021/acssuschemeng.2c0134910.1021/acssuschemeng.2c01349 ↗
7. 10.1016/j.jpowsour.2022.23182210.1016/j.jpowsour.2022.231822 ↗
8. 10.1016/j.nanoen.2017.01.02810.1016/j.nanoen.2017.01.028 ↗
9. 10.1021/acs.chemrev.9b0042710.1021/acs.chemrev.9b00427 ↗
10. 10.1021/acs.chemrev.0c0010110.1021/acs.chemrev.0c00101 ↗
11. 10.1039/C6NR04162K10.1039/C6NR04162K ↗
12. 10.1039/c4cs00020j10.1039/c4cs00020j ↗
13. 10.1016/j.jeurceramsoc.2021.05.04110.1016/j.jeurceramsoc.2021.05.041 ↗
14. 10.1002/cssc.20210117810.1002/cssc.202101178 ↗
15. 10.1039/D0GC01009J10.1039/D0GC01009J ↗
16. 10.1039/C9EE01548E10.1039/C9EE01548E ↗
17. 10.1016/j.jpowsour.2020.22890510.1016/j.jpowsour.2020.228905 ↗
18. 10.1007/s10832-015-9988-710.1007/s10832-015-9988-7 ↗
19. 10.1021/acsami.6b0905910.1021/acsami.6b09059 ↗
20. 10.1007/s10832-016-0062-x10.1007/s10832-016-0062-x ↗
21. 10.1039/C8SE00436F10.1039/C8SE00436F ↗
22. 10.1016/j.jpowsour.2014.02.10210.1016/j.jpowsour.2014.02.102 ↗
23. 10.1016/j.cej.2022.13881910.1016/j.cej.2022.138819 ↗
24. 10.1039/c3ta11996c10.1039/c3ta11996c ↗
25. 10.1016/j.electacta.2016.11.02010.1016/j.electacta.2016.11.020 ↗
26. 10.1016/j.jpowsour.2013.03.16610.1016/j.jpowsour.2013.03.166 ↗
27. 10.1016/j.elecom.2013.04.00410.1016/j.elecom.2013.04.004 ↗
28. 10.1021/acsami.8b1765610.1021/acsami.8b17656 ↗
29. 10.1016/j.jpcs.2019.10908010.1016/j.jpcs.2019.109080 ↗
30. 10.1039/D2QI00508E10.1039/D2QI00508E ↗
31. 10.1149/1945-7111/ac683610.1149/1945-7111/ac6836 ↗
32. 10.1021/acsami.1c2224610.1021/acsami.1c22246 ↗
33. 10.1002/adem.20200005110.1002/adem.202000051 ↗
34. 10.1016/j.matlet.2019.03.10910.1016/j.matlet.2019.03.109 ↗
35. 10.1016/j.jpowsour.2020.22943010.1016/j.jpowsour.2020.229430 ↗
36. 10.1039/D1CP00359C10.1039/D1CP00359C ↗
37. 10.1016/j.mattod.2021.08.00510.1016/j.mattod.2021.08.005 ↗
38. 10.1017/S143192762201240510.1017/S1431927622012405 ↗
39. 10.2116/analsci.33.85310.2116/analsci.33.853 ↗
40. 10.1016/j.ssi.2019.02.01010.1016/j.ssi.2019.02.010 ↗
41. 10.1039/b922045c10.1039/b922045c ↗
42. 10.1021/acs.analchem.2c0141010.1021/acs.analchem.2c01410 ↗
43. 10.1038/nmeth.208910.1038/nmeth.2089 ↗
44. 10.1016/j.jpowsour.2022.23187210.1016/j.jpowsour.2022.231872 ↗
45. 10.1016/j.jpowsour.2011.04.04710.1016/j.jpowsour.2011.04.047 ↗
46. 10.1021/acs.chemmater.6b0387010.1021/acs.chemmater.6b03870 ↗
47. 10.1021/acsaem.0c0247410.1021/acsaem.0c02474 ↗
48. 10.1021/acsami.8b0670510.1021/acsami.8b06705 ↗
49. 10.1107/S056773947600155110.1107/S0567739476001551 ↗
50. 10.1002/jrs.566910.1002/jrs.5669 ↗
51. 10.1557/JMR.2001.000110.1557/JMR.2001.0001 ↗
52. 10.1103/PhysRevB.97.07514310.1103/PhysRevB.97.075143 ↗
53. 10.1016/j.jssc.2005.09.01610.1016/j.jssc.2005.09.016 ↗