Modular Synthesis of Highly Porous Zr-MOFs Assembled from Simple Building Blocks for Oxygen Storage
Source abstract
Abstract
The last decade has witnessed significant advances in the scale-up synthesis of metal–organic frameworks (MOFs) using commercially available and affordable organic linkers. However, the synthesis of MOFs using elongated and/or multitopic linkers to access MOFs with large pore volume and/or various topologies can often be challenging due to multistep organic syntheses involved for linker preparation. In this report, a modular MOF synthesis strategy is developed by utilizing the coordination and covalent bonds formation in one-pot strategy where monoacid-based ligands reacted to form ditopic ligands, which then assembled into a three-dimensional MOF with Zr6 clusters. Chemical stability of the resulting materials was significantly enhanced through converting the imine bond into robust linkage via cycloaddition with phenylacetylene. Oxygen storage capacities of the MOFs were measured, and enhanced volumetric O2 uptake was observed for the stabilized MOF, NU-401-Q.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · MXene and MAX Phase Materials · Machine Learning in Materials Science
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Pharmaceutical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
Key Laboratory of Systems Bioengineering, Ministry of Education, Tianjin University, Tianjin 300350, China
Department of Chemistry and International Institute of Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States
Department of Chemical and Biological Engineering, Colorado School of Mines, Golden, Colorado 80401, United States
Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States
Funding
Defense Threat Reduction Agency · Division of Chemical, Bioengineering, Environmental, and Transport Systems
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