journal article·2014-08-13

Fabrication of Transparent-Conducting-Oxide-Coated Inverse Opals as Mesostructured Architectures for Electrocatalysis Applications: A Case Study with NiO

Vennesa O. Williams, Erica J. DeMarco, Michael J. Katz, Joseph A. Libera, Shannon C. Riha, Dong Wook Kim, Jason R. Avila, Alex B. F. Martinson, Jeffrey W. Elam, Michael J. Pellin, Omar K. Farha, Joseph T. Hupp

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Abstract

Highly ordered, and conductive inverse opal arrays were made with silica and subsequently coated with tin-doped indium oxide (ITO) via atomic layer deposition (ALD). We demonstrate the utility of the resulting mesostructured electrodes by further coating them with nickel oxide via ALD. The NiO-coated arrays are capable of efficiently electrochemically evolving oxygen from water. These modular, crack-free, transparent, high surface area, and conducting structures show promise for many applications including electrocatalysis, photocatalysis, and dye-sensitized solar cells.
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OpenAlex topics: Photonic Crystals and Applications · Quantum Dots Synthesis And Properties · Copper-based nanomaterials and applications

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Affiliations

Department of Chemistry and Argonne-Northwestern Solar Energy Research Center (ANSER), Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States

Materials Science Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, United States

Energy Systems Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, United States

Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

Chemical Science and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, United States

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