Supramolecular Polymeric Pressure-Sensitive Adhesive That Can Be Directly Operated at Low Temperatures

Low-temperature adhesion is ubiquitous in daily life and industry. However, most supramolecular adhesives are thermoplastic materials that require heating during the adhesion. Herein, a supramolecular approach is used to construct unique pressure-sensitive adhesives (PSAs) that can be directly operated at low temperatures (−60 °C). Supramolecular polymerization between phytic acid (PA) and water (H) endows poly(PA-H)s with excellent mechanical properties and low temperature adhesion capacity. Poly(PA-H)s can easily be processed into PSA tapes, pastes, and particles. Poly(PA-H)s were directly adhered to various surfaces by pressing at low temperatures (0 to −60 °C). No heating or high-temperature-induced solid–liquid transition was required for the low-temperature adhesion of poly(PA-H)s. With the help of structural water units in supramolecular polymers, poly(PA-H)s showed strong, stable, and organic solvent resistant adhesion performances at low temperatures, with adhesion strength of up to 3.61 MPa at −60 °C.