Stimuli-Responsive Self-Assembly of π-Conjugated Liquids Triggers Circularly Polarized Luminescence

Ayumi Ikenaga; Yuichi Akiyama; Tatsuya Ishiyama; Masayuki Gon; Kazuo Tanaka; Yoshiki Chujo; Kyosuke Isoda

doi:10.1021/acsami.1c13119

journal article·2021-10-06

Stimuli-Responsive Self-Assembly of π-Conjugated Liquids Triggers Circularly Polarized Luminescence

Ayumi Ikenaga, Yuichi Akiyama, Tatsuya Ishiyama, Masayuki Gon, Kazuo Tanaka, Yoshiki Chujo, Kyosuke Isoda

ACS Applied Materials & Interfaces· Volume 13· Issue 39

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Abstract

We developed novel room-temperature stimuli-responsive N-heteroacene-based liquid materials bearing a chiral alkyl chain. When these liquid materials were exposed to HCl vapor as an external stimulus, a disordered–ordered state change occurred immediately to yield self-assembled solid states from fluidic liquids. The self-assembly mechanism during this state change was evaluated by experimental in situ observations and molecular dynamics simulations over various spatiotemporal scales. These self-assembled structures led to supramolecular chirality through the influence of the chiral alkyl chain. As a result, circularly polarized luminescence (CPL) was triggered in the solid state, which was absent in the precursor liquid, thereby rendering this the first report on a stimuli-responsive CPL on/off liquid material. In addition, the initial state was recovered by exposure to air or upon heating. Moreover, the synergy between the experimental and the theoretical studies opens a new avenue to develop a novel class of stimuli-responsive materials and to discover novel phenomena in such materials.

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Research context

OpenAlex topics: Synthesis and Properties of Aromatic Compounds · Luminescence and Fluorescent Materials · Polydiacetylene-based materials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Division of Advanced Materials Science, Graduate School of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, Japan

Department of Applied Chemistry, Graduate School of Science and Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan

Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Program in Advanced Materials Science, Faculty of Engineering and Design, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, Japan

Health and Medical Research Institute, National Institute of Advanced Industrial Science and Technology, 2217-14 Hayashi-cho, Takamatsu, Kagawa 761-0395, Japan

Funding

Kagawa University · Japan Society for the Promotion of Science · Takahashi Industrial and Economic Research Foundation · Academic Culture Promotion Foundation · Tokyo Kasei Chemical Promotion Foundation · Hyakujushi Bank · Nankai Foundation

References (54)

Show source-provided references

1. 10.1002/anie.20190314810.1002/anie.201903148 ↗

2. Nakanishi T. · 201910.1002/9783527804948 ↗

3. 10.1002/adom.20190017610.1002/adom.201900176 ↗

4. 10.1021/acsami.8b2169510.1021/acsami.8b21695 ↗

5. 10.1002/anie.20181183410.1002/anie.201811834 ↗

6. 10.1002/asia.20180063110.1002/asia.201800631 ↗

7. 10.1021/ja411316s10.1021/ja411316s ↗

8. 10.1038/ncomms296910.1038/ncomms2969 ↗

9. 10.1039/d0tc04234j10.1039/d0tc04234j ↗

10. 10.1039/c9mh01041f10.1039/c9mh01041f ↗

11. 10.1021/jacs.0c0645410.1021/jacs.0c06454 ↗

12. 10.1002/anie.20191666610.1002/anie.201916666 ↗

13. 10.1021/jacs.9b1108010.1021/jacs.9b11080 ↗

14. 10.1002/anie.20190289010.1002/anie.201902890 ↗

15. 10.1021/acscentsci.9b0017310.1021/acscentsci.9b00173 ↗

16. 10.1038/s41467-018-05744-x10.1038/s41467-018-05744-x ↗

17. 10.1021/jacs.8b0378110.1021/jacs.8b03781 ↗

18. 10.1038/ncomms788410.1038/ncomms7884 ↗

19. 10.1038/ncomms300910.1038/ncomms3009 ↗

20. 10.1038/nchem.41110.1038/nchem.411 ↗

21. 10.1021/ja067736210.1021/ja0677362 ↗

22. 10.1038/nmat145410.1038/nmat1454 ↗

23. 10.1002/1521-4095(20021118)14:22<1625::aid-adma1625>3.0.co;2-q10.1002/1521-4095(20021118)14:22<1625::aid-adma1625>3.0.co;2-q ↗

24. 10.1039/c9tc05195c10.1039/c9tc05195c ↗

25. 10.1002/adma.20190011010.1002/adma.201900110 ↗

26. 10.1002/chem.20190325210.1002/chem.201903252 ↗

27. 10.1039/c8sc04026e10.1039/c8sc04026e ↗

28. 10.1038/s41570-017-004510.1038/s41570-017-0045 ↗

29. 10.1021/acs.jpclett.5b0145210.1021/acs.jpclett.5b01452 ↗

30. 10.1039/c5tc00705d10.1039/c5tc00705d ↗

31. 10.1039/c5cc01465d10.1039/c5cc01465d ↗

32. 10.1039/c4cc03944k10.1039/c4cc03944k ↗

33. 10.1021/ja412197j10.1021/ja412197j ↗

34. 10.1351/pac-con-12-11-0910.1351/pac-con-12-11-09 ↗

35. 10.1002/anie.20120533210.1002/anie.201205332 ↗

36. 10.1021/ja203206g10.1021/ja203206g ↗

37. 10.1146/annurev.matsci.27.1.30510.1146/annurev.matsci.27.1.305 ↗

38. 10.1002/anie.20201355010.1002/anie.202013550 ↗

39. 10.1002/anie.20210122610.1002/anie.202101226 ↗

40. 10.1126/science.284.5415.78510.1126/science.284.5415.785 ↗

41. 10.1021/ja067321g10.1021/ja067321g ↗

42. 10.1021/acs.accounts.0c0011210.1021/acs.accounts.0c00112 ↗

43. 10.1038/ncomms795910.1038/ncomms7959 ↗

44. 10.1039/c9tc06105c10.1039/c9tc06105c ↗

45. 10.1021/acsami.0c1724110.1021/acsami.0c17241 ↗

46. 10.1002/open.20170000710.1002/open.201700007 ↗

47. 10.1021/ar50056a00110.1021/ar50056a001 ↗

48. 10.1039/b515476f10.1039/b515476f ↗

49. 10.1002/jcc.2003510.1002/jcc.20035 ↗

50. 10.1063/1.32869310.1063/1.328693 ↗

51. 10.1063/1.44733410.1063/1.447334 ↗

52. 10.1103/physreva.31.169510.1103/physreva.31.1695 ↗

53. 10.1063/1.46439710.1063/1.464397 ↗

54. 10.1002/jcc.2029110.1002/jcc.20291 ↗