Temperature-Dependent Li Storage Performance in Nanoporous Cu–Ge–Al Alloy

The performance fading process and safety concerns of lithium ion batteries at low temperature (LT) prohibit their application in cold climates. The alloy-type electrodes demonstrate great potentials in stable and dendrite-free anodes at LT. Herein, we report a temperature-dependent Li storage performance in Al-based nanoporous alloy anode. The nanoporous-structured Cu-Ge-Al ternary alloys (NP-CuGeAl) have been designed and prepared by selectively etching Al out. The high-Al-content NP-CuGeAl (acid etching for 6 h, named CGA-6) is composed of multi-intermetallic compounds (denoted as M _xN _y, M, N = Cu, Al, Ge) with bimodal porous architectures. Investigated as anode at room temperature, the CGA-6 delivers a capacity as high as 479.7 mAh g^-1 at 0.5 A g^-1 of over 1020 cycles, and the low-Al-content ones show improved LT electrochemical performance. At -20 °C, the CGA-48 (acid etching for 48 h) shows much better performance as compared with the CGA-6. In Situ transmission electron microscopy and ex situ characterizations confirm that the M _xN _y/Li _zM _xN _y couples are highly reversible and the porous structure is durable upon battery cycling.