journal article·2017-07-12

Enhancing Mechanical and Thermal Properties of Epoxy Nanocomposites via Alignment of Magnetized SiC Whiskers

James Townsend, Ruslan Burtovyy, Pavel Aprelev, Konstantin G. Kornev, Igor Luzinov

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Abstract

This research is focused on the fabrication and properties of epoxy nanocomposites containing magnetized SiC whiskers (MSiCWs). To this end, we report an original strategy for fabrication of magnetically active SiCWs by decorating the whiskers with magnetic (iron oxide) nanoparticles via polymer-polymer (poly(acrylic acid)/poly(2-vinyl pyridine)) complexation. The obtained whiskers demonstrated a substantial magnetic response in the polymerizing epoxy resin, with application of only a 20 mT (200 G) magnetic field. We also found that the whiskers chemically reacted with the epoxy resin, causing formation of an extended interphase near the boundary of the whiskers. The SiC whiskers oriented with the magnetic field demonstrated positive effects on the behavior of epoxy-based nanocomposites. Namely, the aligned MSiCWs enhanced the thermomechanical properties of the materials significantly above that of the neat epoxy and epoxy nanocomposite, with randomly oriented whiskers.
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Research context

OpenAlex topics: Electromagnetic wave absorption materials · Polymer Nanocomposites and Properties · Additive Manufacturing and 3D Printing Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, Clemson University, 161 Sirrine Hall, Clemson, South Carolina 29626, United States

Funding

Air Force Office of Scientific Research

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