Facile and Scalable Synthesis of Self-Supported Zn-Doped CuO Nanosheet Arrays for Efficient Nitrate Reduction to Ammonium

CuO has been regarded as a promising catalyst for the electrochemical reduction of nitrate (NO 3 – RR) to ammonium (NH 3 ); however, the intrinsic activity is greatly restricted by its poor electrical property. In this work, self-supported Zn-doped CuO nanosheet arrays (Zn–CuO NAs) are synthesized for NO 3 – RR, where the Zn dopant regulates the electronic structure of CuO to significantly accelerate the interfacial charge transfer and inner electron transport kinetics. The Zn–CuO NAs are constructed by a one-step etching of commercial brass (Cu 64 Zn 36 alloy) in 0.1 M NaOH solution, which experiences a corrosion–oxidation–reconstruction process. Initially, the brass undergoes a dealloying procedure to produce nanosized Cu, which is immediately oxidized to the Cu 2 O unit with a low valence state. Subsequently, Cu 2 O is further oxidized to the CuO unit and reconstructed into nanosheets with the coprecipitation of Zn 2+ . For NO 3 – RR, Zn–CuO NAs show a high NH 3 production rate of 945.1 μg h –1 cm –2 and a Faradaic efficiency of up to 95.6% at −0.7 V in 0.1 M Na 2 SO 4 electrolyte with 0.01 M NaNO 3, which outperforms the majority of the state-of-the-art catalysts. The present work offers a facile yet very efficient strategy for the scale-up synthesis of Zn–CuO NAs for high-performance NH 3 production from NO 3 – RR.