DataVXACS Applied Materials & InterfacesPaper
journal article·2020-12-09Open access

Postsynthetic Metalated MOFs as Atomically Dispersed Catalysts for Hydroformylation Reactions

Panjuan Tang, Stefano Paganelli, Francesco Carraro, Matias Blanco, Raffaele Riccò, Carla Marega, Denis Badocco, Paolo Pastore, Christian J. Doonan, Stefano Agnoli

ACS Applied Materials & Interfaces· Volume 12· Issue 49
Publisher pageOpen full text
Source abstract

Abstract

A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
Source: openalex_inverted_index · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes · Dendrimers and Hyperbranched Polymers

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Sciences and INSTM Unit, University of Padova, Via F. Marzolo 1, 35131 Padova, Italy

Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, 30172 Venezia Mestre, Italy

Institute of Physical and Theoretical Chemistry, Graz University of Technology, Graz 8010, Austria

Department of Chemistry, University of Adelaide, Adelaide, South Australia 5005, Australia

Funding

H2020 Marie Sklodowska-Curie Actions · Technische Universit?t Graz · China Scholarship Council · Universit? degli Studi di Padova · Italy-US Fulbright Commission

References (40)

Show source-provided references
1. Cornils B. · 200210.1002/9783527618231 ↗
2. van Leeuwen P. W. N. M. · 200210.1007/0-306-46947-2 ↗
3. 10.1021/cr300180310.1021/cr3001803 ↗
4. 10.1021/cr900392410.1021/cr9003924 ↗
5. 10.1016/s1369-7021(06)71388-810.1016/s1369-7021(06)71388-8 ↗
6. Barbaro P. · 201010.1007/978-90-481-3696-4 ↗
7. 10.1007/s11705-017-1672-910.1007/s11705-017-1672-9 ↗
8. 10.1007/s11144-014-0788-x10.1007/s11144-014-0788-x ↗
9. 10.1016/s0008-6223(97)00173-510.1016/s0008-6223(97)00173-5 ↗
10. 10.1021/acs.chemmater.8b0131110.1021/acs.chemmater.8b01311 ↗
11. 10.1039/b807080f10.1039/b807080f ↗
12. 10.1039/c7ce90106b10.1039/c7ce90106b ↗
13. 10.1021/ja402577s10.1021/ja402577s ↗
14. 10.1039/c7cc09173g10.1039/c7cc09173g ↗
15. 10.1039/c7cc05927b10.1039/c7cc05927b ↗
16. 10.1016/j.apcata.2013.09.01110.1016/j.apcata.2013.09.011 ↗
17. 10.1016/j.micromeso.2013.02.03510.1016/j.micromeso.2013.02.035 ↗
18. 10.1007/s12274-014-0501-410.1007/s12274-014-0501-4 ↗
19. 10.1039/c2cs35047e10.1039/c2cs35047e ↗
20. 10.1038/nchem.127210.1038/nchem.1272 ↗
21. 10.1039/c4cc01607f10.1039/c4cc01607f ↗
22. 10.1039/c3ce41244j10.1039/c3ce41244j ↗
23. 10.1038/nchem.204510.1038/nchem.2045 ↗
24. 10.1002/ange.20161125410.1002/ange.201611254 ↗
25. 10.1016/j.tca.2008.04.01510.1016/j.tca.2008.04.015 ↗
26. 10.1039/a807821a10.1039/a807821a ↗
27. 10.1002/jrs.125019040410.1002/jrs.1250190404 ↗
28. 10.1021/ja00367a00110.1021/ja00367a001 ↗
29. 10.1016/s0020-1693(00)80566-610.1016/s0020-1693(00)80566-6 ↗
30. Kamer P. J. K. · 201210.1002/9781118299715 ↗
31. 10.1016/s0010-8545(99)00127-710.1016/s0010-8545(99)00127-7 ↗
32. 10.1002/ejoc.20120070910.1002/ejoc.201200709 ↗
33. 10.1021/acs.chemmater.8b0183110.1021/acs.chemmater.8b01831 ↗
34. 10.1021/jacs.6b1253310.1021/jacs.6b12533 ↗
35. 10.1126/science.108367110.1126/science.1083671 ↗
36. 10.1016/j.chempr.2016.07.00510.1016/j.chempr.2016.07.005 ↗
37. 10.1021/jacs.5b0295610.1021/jacs.5b02956 ↗
38. 10.1021/acs.accounts.8b0029710.1021/acs.accounts.8b00297 ↗
39. 10.1021/acs.accounts.9b0060910.1021/acs.accounts.9b00609 ↗
40. Carraro, F. Multiscale Design of Nanostructured Materials for Catalysis. Ph.D. Thesis, Doctorate School of Science and Engineering of Materials and Nanostructures, University of Padova, Italy 2018.