Large-Scale Production of Nanocrystalline Black Phosphorus Ceramics

Nikolas Antonatos; Daniel Bouša; Evgeniya Kovalska; David Sedmidubský; Květoslav Růžička; Pavel Vrbka; Martin Veselý; Jiří Hejtmánek; Zdeněk Sofer

doi:10.1021/acsami.9b13362

journal article·2020-02-12

Large-Scale Production of Nanocrystalline Black Phosphorus Ceramics

Nikolas Antonatos, Daniel Bouša, Evgeniya Kovalska, David Sedmidubský, Květoslav Růžička, Pavel Vrbka, Martin Veselý, Jiří Hejtmánek, Zdeněk Sofer

ACS Applied Materials & Interfaces· Volume 12· Issue 6

Publisher page

Source abstract

Abstract

Black phosphorus is currently among the most explored two-dimensional (2D) materials. Currently, the synthesis methods are dominantly based on vapor-phase growth of black phosphorus. In this manuscript, we demonstrate large-scale synthesis of black phosphorus by rapid high-pressure transition of red phosphorus. The high-pressure conversion of red phosphorus led to high-density nanocrystalline black phosphorus ceramics. The resulting material was explored in detail including structural and morphological characterization in addition to thermal and electrical transport and basic thermophysical properties. The nanocrystalline black phosphorus can be employed for large-scale production of stable few/single-layer black phosphorus colloidal solutions in various solvents.

Source: openalex_inverted_index · Quality: baseline

Research context

Ceramics & glasses Nanomaterials

OpenAlex topics: 2D Materials and Applications · MXene and MAX Phase Materials · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Inorganic Chemistry, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague 6, Prague, Czech Republic

Department of Physical Chemistry, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague 6, Prague, Czech Republic

Department of Organic Technology, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague 6, Prague, Czech Republic

Institute of Physics of the Czech Academy of Sciences, v.v.i., Cukrovarnická 112/10, 162 00 Prague 6, Prague, Czech Republic

Funding

Grantov? Agentura Cesk? Republiky

References (67)

Show source-provided references

1. 10.1063/1.43852310.1063/1.438523 ↗

2. 10.1143/JPSJ.50.336210.1143/JPSJ.50.3362 ↗

3. 10.1103/PhysRevLett.112.17680110.1103/PhysRevLett.112.176801 ↗

4. 10.1021/nl502865s10.1021/nl502865s ↗

5. 10.1021/nn501226z10.1021/nn501226z ↗

6. 10.1038/ncomms545810.1038/ncomms5458 ↗

7. 10.1038/nmat429910.1038/nmat4299 ↗

8. 10.1103/PhysRevB.91.15531110.1103/PhysRevB.91.155311 ↗

9. 10.1021/nl504376910.1021/nl5043769 ↗

10. 10.1039/C5NR04366B10.1039/C5NR04366B ↗

11. 10.1002/anie.20160516810.1002/anie.201605168 ↗

12. 10.1002/adma.20150573010.1002/adma.201505730 ↗

13. 10.1021/jz500409m10.1021/jz500409m ↗

14. 10.1039/C3TA10380C10.1039/C3TA10380C ↗

15. 10.1021/acsami.5b1024710.1021/acsami.5b10247 ↗

16. 10.1021/acs.jpclett.5b0109410.1021/acs.jpclett.5b01094 ↗

17. 10.1038/nnano.2015.11210.1038/nnano.2015.112 ↗

18. 10.1002/anie.20150501510.1002/anie.201505015 ↗

19. 10.1002/celc.20140236310.1002/celc.201402363 ↗

20. 10.1038/srep0645210.1038/srep06452 ↗

21. 10.1063/1.490563610.1063/1.4905636 ↗

22. 10.1038/nmat237810.1038/nmat2378 ↗

23. 10.1063/1.492255110.1063/1.4922551 ↗

24. 10.1002/anie.20140940010.1002/anie.201409400 ↗

25. 10.1002/adma.20100381910.1002/adma.201003819 ↗

26. 10.1002/smll.20140098810.1002/smll.201400988 ↗

27. 10.1038/nnano.2012.6010.1038/nnano.2012.60 ↗

28. 10.1002/adom.20160021410.1002/adom.201600214 ↗

29. 10.1021/ja02184a00210.1021/ja02184a002 ↗

30. 10.1103/PhysRev.3.48910.1103/PhysRev.3.489 ↗

31. 10.1021/ja02260a00810.1021/ja02260a008 ↗

32. 10.1021/jp302265n10.1021/jp302265n ↗

33. 10.1143/JJAP.21.L48210.1143/JJAP.21.L482 ↗

34. 10.1143/JPSJ.52.214810.1143/JPSJ.52.2148 ↗

35. 10.1002/zaac.1955280011010.1002/zaac.19552800110 ↗

36. 10.1107/S0365110X6500414010.1107/S0365110X65004140 ↗

37. 10.1016/j.jssc.2008.03.00810.1016/j.jssc.2008.03.008 ↗

38. 10.1016/j.jcrysgro.2014.07.02910.1016/j.jcrysgro.2014.07.029 ↗

39. 10.3389/fchem.2019.0002110.3389/fchem.2019.00021 ↗

40. 10.1002/adma.20060259210.1002/adma.200602592 ↗

41. Höhne G. W. H. · 200310.1007/978-3-662-06710-9 ↗

42. 10.1016/j.jct.2014.04.02210.1016/j.jct.2014.04.022 ↗

43. 10.1103/PhysRevB.60.1405710.1103/PhysRevB.60.14057 ↗

44. 10.1016/j.jmmm.2018.07.00610.1016/j.jmmm.2018.07.006 ↗

45. 10.1016/0038-1098(85)90213-310.1016/0038-1098(85)90213-3 ↗

46. 10.1021/acsami.5b0129710.1021/acsami.5b01297 ↗

47. 10.1021/nl503229310.1021/nl5032293 ↗

48. 10.1063/1.486813210.1063/1.4868132 ↗

49. 10.1038/ncomms956310.1038/ncomms9563 ↗

50. 10.1088/2053-1583/2/1/01100210.1088/2053-1583/2/1/011002 ↗

51. 10.1038/s41699-017-0023-510.1038/s41699-017-0023-5 ↗

52. 10.1021/acs.chemmater.6b0359210.1021/acs.chemmater.6b03592 ↗

53. 10.1088/2053-1583/1/2/02500110.1088/2053-1583/1/2/025001 ↗

54. 10.1103/PhysRevLett.114.04680110.1103/PhysRevLett.114.046801 ↗

55. 10.1088/2053-1583/3/2/02501110.1088/2053-1583/3/2/025011 ↗

56. 10.1021/acscentsci.5b0024410.1021/acscentsci.5b00244 ↗

57. 10.1016/0040-6031(88)87196-X10.1016/0040-6031(88)87196-X ↗

58. 10.1039/tf962580191610.1039/tf9625801916 ↗

59. 10.1103/PhysRevB.15.262410.1103/PhysRevB.15.2624 ↗

60. 10.1016/0021-9614(69)90037-810.1016/0021-9614(69)90037-8 ↗

61. 10.1126/sciadv.aat337410.1126/sciadv.aat3374 ↗

62. 10.1103/PhysRev.139.A50710.1103/PhysRev.139.A507 ↗

63. 10.1039/C4CP04858J10.1039/C4CP04858J ↗

64. 10.1021/acs.chemmater.7b0462810.1021/acs.chemmater.7b04628 ↗

65. 10.1039/C3CS60217F10.1039/C3CS60217F ↗

66. 10.1039/C6CC03206K10.1039/C6CC03206K ↗

67. 10.1002/adma.20140515010.1002/adma.201405150 ↗