Nucleotide-Based Assemblies for Green Synthesis of Silver Nanoparticles with Controlled Localized Surface Plasmon Resonances and Their Applications

The sizes, shapes, and surface characteristics of nanomaterials determine their unique physical, chemical, and biological properties. Localized surface plasmon resonance (LSPR) is one of the unique optical properties of noble-metal nanoparticles. The synthesis of nanomaterials using biomolecules as templates offers an excellent strategy to control and regulate their features. Herein, for the first time, we demonstrate a green synthesis approach of silver nanoparticles (AgNPs) using nucleotide-based assemblies as templates. Moreover, we investigate the influence of different nucleotide-based assemblies and metal ions on the preparation of AgNPs, implying that AgNPs with different LSPR absorptions originating from their surrounding and size could be synthesized. The synthetic route is green, energy-effective, and feasible. On the basis of the unique LSPR-controlled property, the AgNP composites were applied for cryptography, biothiol detection, and designing logic gates. This work offers a promising method for the synthesis of nanomaterials with multiapplications.