Electrorheology of Polystyrene Filler/Polyhedral Silsesquioxane Suspensions

An important challenge in the field of electrorheology is identifying low-viscosity fluids that would exhibit significant changes in viscosity, or a yield stress, upon the application of an external electric field. Our recent research showed that optimal compositions of mixtures, 10 wt % sulfonated polyhedral oligomeric silsesquioxanes (s-POSS) mixed with polydimethyl siloxane (PDMS), exhibited significant electrorheological activity. Here we show that s-POSS/PDMS mixtures containing polystyrene (PS) fillers, of micrometer-sized dimensions, containing as little as ~1 wt % s-POSS, exhibited an increase in ER activity by an order of magnitude, beyond that of s-POSS/PDMS mixtures. The dynamic yield stress was found to scale with the particle diameter, a, as τ(y) is proportional to a(0.5) and with the electric field as τ(y) is proportional to E(1.5-2.5); this behavior is reasonably well understood within the context of dielectric electrorheological theory.