Evaluation of Mg[B(HFIP)₄]₂-Based Electrolyte Solutions for Rechargeable Mg Batteries

/DME solutions were found to enable reversible Mg deposition, albeit with a relatively low Coulombic efficiency of 95% during the first cycles. Prolonged deposition/dissolution cycling tests demonstrate a stable behavior of magnesium electrodes. Overall, this system presents a reasonable electrolyte solution and can serve as a basis for future efforts to develop chlorine-free alternatives for secondary magnesium batteries. It is clear that such a conditioning process is mandatory, as it removes reactive contaminants that lead to unavoidable passivation and deactivation of Mg electrodes from the solution.