journal article·2017-04-05Open access

Temperature-Controlled Three-Stage Switching of Wetting, Morphology, and Protein Adsorption

Yurij Stetsyshyn, Joanna Raczkowska, Ostap Lishchynskyi, Andrzej Bernasik, Andrij Kostruba, Khrystyna Harhay, Halyna Ohar, Mateusz M. Marzec, Andrzej Budkowski

Abstract

The novel polymeric coatings of oligoperoxide-graft-poly(4-vinylpyridine-co-oligo(ethylene glycol)ethyl ether methacrylate246) [oligoperoxide-graft-P(4VP-co-OEGMA246)] attached to glass were successfully fabricated. The composition, thickness, morphology, and wettability of resulting coatings were analyzed using X-ray photoelectron spectroscopy, ellipsometry, atomic force microscopy, and contact angle measurements, respectively. In addition, adsorption of the bovine serum albumin was examined with fluorescence microscopy. The thermal response of wettability and morphology of the coatings followed by that of protein adsorption revealed two distinct transitions at 10 and 23 °C. For the first time, three stage switching was observed not only for surface wetting but also for morphology and protein adsorption. Moreover, the influence of the pH on thermo-sensitivity of modified surfaces was shown.
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Research context

OpenAlex topics: Polymer Surface Interaction Studies · Nanofabrication and Lithography Techniques · Surface Modification and Superhydrophobicity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Lviv Polytechnic National University, S. Bandery 12, 79013 Lviv, Ukraine

Smoluchowski Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348 Kraków, Poland

Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, Al. Mickiewicza 30, 30-049 Kraków, Poland

Academic Centre for Materials and Nanotechnology, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, Poland

Lviv Academy of Commerce, Samtshuk 9, 79011 Lviv, Ukraine

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