Doubly Interpenetrated Metal–Organic Framework of pcu Topology for Selective Separation of Propylene from Propane
Source abstract
Abstract
Adsorptive separation is an appealing alternative technology to reduce the high energy and capital cost of the distillation separation of propylene/propane; however, it is very challenging to realize. A new flexible metal–organic framework (MOF) material [Zn2(BDC-Cl)2(Py2TTz)] with a doubly interpenetrated pillared paddle wheel structure of pcu (primitive cubic) topology has been realized for this difficult separation for the first time. Through a judicious choice of linkers, the framework has small pore apertures that lead to much more propylene adsorption than propane. The selective adsorption relies on the sieving effect of the flexible framework. The column breakthrough experiment further demonstrated that efficient separation can be achieved under dynamic conditions.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Zeolite Catalysis and Synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Chemistry and Materials Science, and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, P. R. China
Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, United States
The Molecular Foundry, Lawrence Berkeley National Laboratory Berkeley, Berkeley, California 94720, United States
Funding
Welch Foundation · National Nature Science Foundation of China
References (53)
Show source-provided references
1. 10.1002/14356007.a21_487.pub210.1002/14356007.a21_487.pub2 ↗
2. 10.1021/acs.iecr.7b0343210.1021/acs.iecr.7b03432 ↗
3. 10.1038/532435a10.1038/532435a ↗
4. 10.1021/ie00022a00110.1021/ie00022a001 ↗
5. 10.1002/adma.20180751310.1002/adma.201807513 ↗
6. 10.1002/aic.1449610.1002/aic.14496 ↗
7. 10.1016/j.micromeso.2003.09.02510.1016/j.micromeso.2003.09.025 ↗
8. 10.1126/science.123044410.1126/science.1230444 ↗
9. 10.1021/acs.chemrev.9b0082810.1021/acs.chemrev.9b00828 ↗
10. 10.1016/j.ccr.2018.11.00910.1016/j.ccr.2018.11.009 ↗
11. 10.1016/j.chempr.2018.12.01110.1016/j.chempr.2018.12.011 ↗
12. 10.1016/j.ccr.2020.21350710.1016/j.ccr.2020.213507 ↗
13. 10.1021/acs.chemrev.9b0025710.1021/acs.chemrev.9b00257 ↗
14. 10.1016/j.enchem.2019.10000610.1016/j.enchem.2019.100006 ↗
15. 10.1126/science.aaz888110.1126/science.aaz8881 ↗
16. 10.1002/adma.20190799510.1002/adma.201907995 ↗
17. 10.1016/j.chempr.2019.10.01210.1016/j.chempr.2019.10.012 ↗
18. 10.1039/C9CS00756C10.1039/C9CS00756C ↗
19. 10.1016/j.trechm.2019.02.01210.1016/j.trechm.2019.02.012 ↗
20. 10.1039/C7CS00153C10.1039/C7CS00153C ↗
21. 10.1126/science.aam723210.1126/science.aam7232 ↗
22. 10.1002/ejic.20190055110.1002/ejic.201900551 ↗
23. 10.1021/jacs.9b1092310.1021/jacs.9b10923 ↗
24. 10.1016/j.mtnano.2018.09.00310.1016/j.mtnano.2018.09.003 ↗
25. 10.1002/adma.20190827510.1002/adma.201908275 ↗
26. 10.1002/anie.20190220910.1002/anie.201902209 ↗
27. 10.1016/j.cej.2018.08.10810.1016/j.cej.2018.08.108 ↗
28. 10.1126/science.121754410.1126/science.1217544 ↗
29. 10.1002/adma.20170537410.1002/adma.201705374 ↗
30. 10.1126/science.aaf632310.1126/science.aaf6323 ↗
31. 10.1002/adma.20170421010.1002/adma.201704210 ↗
32. 10.1038/s41563-018-0206-210.1038/s41563-018-0206-2 ↗
33. 10.1002/chem.20040120110.1002/chem.200401201 ↗
34. 10.1021/ic050452i10.1021/ic050452i ↗
35. 10.1021/jp013041610.1021/jp0130416 ↗
36. 10.1002/anie.20050284410.1002/anie.200502844 ↗
37. 10.1002/ange.20046071210.1002/ange.200460712 ↗
38. 10.1021/ic060437t10.1021/ic060437t ↗
39. 10.1002/anie.20190997710.1002/anie.201909977 ↗
40. 10.1002/anie.20200318610.1002/anie.202003186 ↗
41. 10.1002/anie.20039013010.1002/anie.200390130 ↗
42. 10.1002/anie.20190416010.1002/anie.201904160 ↗
43. 10.1021/jacs.7b0426810.1021/jacs.7b04268 ↗
44. 10.1039/C8EE00459E10.1039/C8EE00459E ↗
45. 10.1093/nsr/nwx12710.1093/nsr/nwx127 ↗
46. 10.1038/s41467-020-16527-810.1038/s41467-020-16527-8 ↗
47. 10.1016/j.cej.2017.07.04410.1016/j.cej.2017.07.044 ↗
48. 10.1021/jacs.7b0385010.1021/jacs.7b03850 ↗
49. 10.1007/s11426-016-0040-110.1007/s11426-016-0040-1 ↗
50. 10.1002/anie.20180082010.1002/anie.201800820 ↗
51. 10.1080/08927022.2011.59283210.1080/08927022.2011.592832 ↗
52. 10.1021/cg200988w10.1021/cg200988w ↗
53. 10.1016/j.ces.2014.08.05210.1016/j.ces.2014.08.052 ↗