journal article·2017-09-27

High-Performance Nano-Photoinitiators with Improved Safety for 3D Printing

Yanyang Han, Fei Wang, Chin Yan Lim, Hong Chi, Dairong Chen, FuKe Wang, Xiuling Jiao

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Abstract

In this work, we report the first hybrid nanosized photoinitiators with low cytotoxicity and migration by coupling of polyhedral oligomeric silsesquioxanes (POSS) to benzophenone derivatives. This new series of photoinitiators were fully characterized and showed many favorable properties such as uniform sizes, extremely low tendency to migrate, less effect on resin viscosity, enhanced thermal stability and mechanical strength, increased photoactivity, and significantly lower cell toxicity compared to their corresponding benzophenone molecules. The utility of these hybrid nanosized photoinitiators in 3D printing was demonstrated in printing of various 3D structures with high resolution and accuracy.
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Research context

OpenAlex topics: Photopolymerization techniques and applications · Silicone and Siloxane Chemistry · Additive Manufacturing and 3D Printing Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry & Chemical Engineering, Shandong University, Jinan 250100, P. R. China

Polymeric Materials Department, Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, #08-03 Innovis, 138634 Singapore

Institute of Medical Biology, Agency for Science, Technology and Research (A*STAR), 8a Biomedical Grove, #06-06, 138648, Singapore

Shandong Provincial Key Laboratory of Fine Chemicals, School of Chemistry of Pharmaceutical Engineering, Qilu University of Technology, Jinan 250353, China

Funding

Science and Engineering Research Council

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