journal article·2014-05-28

pH-Controlled Selective Etching of Al2O3 over ZnO

Kaige G. Sun, Yuanyuan V. Li, David B. Saint John, Thomas N. Jackson

Publisher page

Abstract

We describe pH-controlled selective etching of atomic layer deposition (ALD) Al2O3 over ZnO. Film thickness as a function of etch exposure was measured by spectroscopic ellipsometry. We find that alkaline aqueous solutions with pH between about 9 and 12 will etch Al2O3 at useful rate with minimal attack of ZnO. Highly selective etching of Al2O3 over ZnO (selectivity >400:1) and an Al2O3 etch rate of ∼50 nm/min can be obtained using a pH 12 etch solution at 60 °C.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: ZnO doping and properties · Semiconductor materials and devices · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Center for Thin Film Devices and Materials Research Institute, ‡Department of Electrical Engineering, and §Department of Material Science Engineering, Penn State University, University Park, Pennsylvania 16802, United States

Funding

National Science Foundation · Dow Chemical Company

References (13)

Show source-provided references
1. Kawamura Y. · J. Dispersion Technol. · 2013 · 9 · 69410.1109/JDT.2012.2213237 ↗
2. Yang J. · Phys. Status Solidi A · 2012 · 209 · 208710.1002/pssa.201228303 ↗
3. Mourey D. A. · J. Soc. Inf. Disp. · 2010 · 18 · 75310.1889/JSID18.10.753 ↗
4. Shinhyuk Y. · IEEE Electron Device Lett. · 2010 · 31 · 14410.1109/LED.2009.2036944 ↗
5. Wang T. · Appl. Phys. Lett. · 2013 · 102 · -
6. Gieraltowska S. · Chem. Vap. Deposition · 2013 · 19 · 21310.1002/cvde.201207029 ↗
7. Kim Y. W. · Sens. Actuators, B · 2012 · 163 · 13610.1016/j.snb.2012.01.021 ↗
8. Mourey D. A. · IEEE Trans. Electron Devices · 2010 · 57 · 53010.1109/TED.2009.2037178 ↗
9. Davidovic D. · Appl. Phys. Lett. · 1998 · 73 · 395910.1063/1.122949 ↗
10. Connors, K. A.Chemical Kinetics: The Study of Reaction Rates in Solution,1st ed.VCH:New York, 1990; p10.
11. Schmidt M. · Science · 2009 · 324 · 8110.1126/science.1165893 ↗
12. Beverskog B. · Corros. Sci. · 1997 · 39 · 10710.1016/S0010-938X(97)89246-3 ↗
13. Li Y. V. · IEEE Electron Device Lett. · 2013 · 34 · 140010.1109/LED.2013.2283337 ↗