Facile Synthesis of Diamino-Modified Graphene/Polyaniline Semi-Interpenetrating Networks with Practical High Thermoelectric Performance
Source abstract
Abstract
p-Phenediamino-modified graphene (PDG) has been newly synthesized via a facile green one-step chemical route as a functionalized graphene-based additive to copolymerize with aniline for fabricating innovative PDG/polyaniline conducting polymer composites containing very special semi-interpenetrating networks (S-IPNs). The S-IPNs not only provide additional pathways by creating chemically bonded PDG and PANI for smoothly transporting carriers but greatly reduce the amount of graphene required to less than a few percent could effectively improve the overall electrical conductivity, Seebeck coefficient, and thus the thermoelectric (TE) performance. The found optimized TE figure of merit (ZT) of 0.74 approaches a practical high level which is comparable or much higher than previously reported ones for TE polymers.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Conducting polymers and applications · Advanced Thermoelectric Materials and Devices · Advanced Battery Materials and Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Materials Science and Engineering, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu, Taiwan 300, R.O.C.
Department of Materials Engineering, Ming Chi University of Technology, 84 Gungjuan Rd., Taishan Dist. New Taipei City, Taiwan 243, R.O.C.
Department of Engineering and System Science, National Tsing Hua University, Sec. 2, Kuang-Fu Road, Hsinchu, Taiwan 300, R.O.C.
Funding
Ministry of Science and Technology, Taiwan
References (37)
Show source-provided references
1. 10.1016/j.matlet.2011.01.01410.1016/j.matlet.2011.01.014 ↗
2. 10.1021/nn100256210.1021/nn1002562 ↗
3. 10.1016/j.cej.2016.03.13710.1016/j.cej.2016.03.137 ↗
4. 10.1002/asia.20140310010.1002/asia.201403100 ↗
5. 10.1007/s11664-013-2745-210.1007/s11664-013-2745-2 ↗
6. 10.1063/1.476195410.1063/1.4761954 ↗
7. 10.1002/aelm.20170018110.1002/aelm.201700181 ↗
8. 10.1063/1.37346910.1063/1.373469 ↗
9. 10.1021/acsami.7b0838210.1021/acsami.7b08382 ↗
10. 10.1021/acsami.7b1010610.1021/acsami.7b10106 ↗
11. 10.1146/annurev.matsci.29.1.8910.1146/annurev.matsci.29.1.89 ↗
12. 10.1126/science.124650110.1126/science.1246501 ↗
13. 10.1021/nn201072m10.1021/nn201072m ↗
14. 10.1021/cm101634k10.1021/cm101634k ↗
15. 10.1039/c1jm11146a10.1039/c1jm11146a ↗
16. 10.1021/ma902862u10.1021/ma902862u ↗
17. 10.1021/nn901047210.1021/nn9010472 ↗
18. 10.1021/nl801384y10.1021/nl801384y ↗
19. 10.1021/jp071761s10.1021/jp071761s ↗
20. 10.1016/j.carbon.2012.03.00110.1016/j.carbon.2012.03.001 ↗
21. 10.1016/j.synthmet.2011.09.04410.1016/j.synthmet.2011.09.044 ↗
22. 10.1016/j.polymer.2012.07.02910.1016/j.polymer.2012.07.029 ↗
23. 10.1039/c3ta12105d10.1039/c3ta12105d ↗
24. 10.1039/c4ta01541j10.1039/c4ta01541j ↗
25. 10.1039/c4ta06422d10.1039/c4ta06422d ↗
26. Wang X. Y. · 2016 · 153
27. 10.1016/j.synthmet.2016.08.01010.1016/j.synthmet.2016.08.010 ↗
28. 10.1088/0957-4484/25/47/47570510.1088/0957-4484/25/47/475705 ↗
29. 10.1039/c5ra01794g10.1039/c5ra01794g ↗
30. 10.1016/j.matchemphys.2012.11.05210.1016/j.matchemphys.2012.11.052 ↗
31. 10.1039/c4nr02765e10.1039/c4nr02765e ↗
32. 10.1063/1.480769710.1063/1.4807697 ↗
33. Grzeszczuk M. · Int. J. Electrochem. Sci. · 2013 · 8 · 895110.1016/S1452-3981(23)12941-5 ↗
34. 10.1021/nn202323210.1021/nn2023232 ↗
35. 10.1080/1532179050047119410.1080/15321790500471194 ↗
36. 10.1002/adma.20030527510.1002/adma.200305275 ↗
37. 10.1016/j.carbon.2011.06.09510.1016/j.carbon.2011.06.095 ↗