A Rational Solid-State Synthesis of Supported Au–Ni Bimetallic Nanoparticles with Enhanced Activity for Gas-Phase Selective Oxidation of Alcohols

A facile confined solid-state seed-mediated alloying strategy is applied for the rational synthesis of supported Au–Ni bimetallic nanoparticles (BMNPs). The method sequentially deposits nickel salts and AuNP seeds into the ordered array of extra-large mesopores (EP-FDU-12 support) followed by a high-temperature annealing process. The size, structure, and composition of the AuNi BMNPs can be well tuned by varying the AuNP seeds, annealing temperature, and feeding ratio of metal precursors. Kinetic studies and DFT calculations suggest that the introduction of the Ni component can significantly prompt the O 2 activation on AuNPs, which is critical for the selective alcohol oxidation using molecular O 2 as the oxidant. The optimal Au–Ni BMNP catalyst showed the highest turnover frequency (TOF) (59 000 h –1, 240 °C) and highest space-time yield (STY) of benzyl aldehyde (BAD) productivity (9.23 kg·g Au –1 ·h –1 ) in the gas-phase oxidation of benzyl alcohol (BA), which is at least about 5-fold higher than that of other supported Au catalysts.