DataVXACS Applied Materials & InterfacesPaper
journal article·2017-10-04

Development of a Porous Coordination Polymer with a High Gas Capacity Using a Thiophene-Based Bent Tetracarboxylate Ligand

Fei Wang, Shinpei Kusaka, Yuh Hijikata, Nobuhiko Hosono, Susumu Kitagawa

ACS Applied Materials & Interfaces· Volume 9· Issue 39
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Source abstract

Abstract

A new porous coordination polymer (PCP) based on a ligand with a unique bent angle bearing a thiophene-bridged bent carboxylate ligand and the Cu 2+ ion was synthesized and structurally characterized. The structure has a pillared-layer framework based on a kagomé-like layer with aromatic partition groups. It exhibits a high CO 2 uptake of 180 mL(STP)/g at 1 bar, and 400 mL(STP)/g at 30 bar at 273 K. The uptakes of C 2 H 2 and C 2 H 4 reach 164 and 160 mL(STP)/g at 298 K and 1 bar, with good selectivity of C 2 H 2 and C 2 H 4 over CH 4, both of which are among the highest levels of reported PCPs.
Source: openalex_inverted_index · Quality: baseline

Research context

Polymers

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Supramolecular Chemistry and Complexes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute for Integrated Cell-Material Sciences, Kyoto University Institute for Advanced Study, Kyoto 606-8501, Japan

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China

Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa-ku, Nagoya, 464-8602, Japan

Funding

Japan Society for the Promotion of Science · Japan Science and Technology Agency · China Scholarship Council · National Natural Science Foundation of China

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