journal article·2020-04-08

Isostructural MOFs with Higher Proton Conductivity for Improved Oxygen Evolution Reaction Performance

Mengxin Zhang, Quanjie Lin, Wangui Wu, Yingxiang Ye, Zizhu Yao, Xiuling Ma, Shengchang Xiang, Zhangjing Zhang

ACS Applied Materials & Interfaces· Volume 12· Issue 14
Publisher page

Abstract

Here we synthesized two new isostructural MOFs (FJU-82-Co/FJU-82-Zn) and first observed that tuning of the proton conductivity may provide an effective strategy to improve the electrocatalytic OER perfomances of isostructural crystalline MOF materials. The conductivity value for FJU-82-Co is 7.40 × 10–5 S cm–1, which is 127-fold that for FJU-82-Zn with 5.80 × 10–7 S cm–1 at 60 °C and 98% RH, while the overpotential of FJU-82-Co is 0.57 V at 1 mA cm–2, which is better than that of FJU-82-Zn with 1.17 V.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Machine Learning in Materials Science · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, P. R. China

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China

Funding

Natural Science Foundation of Fujian Province · National Natural Science Foundation of China

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