journal article·2019-10-30Open access

Effect of Flexibility and Nanotriboelectrification on the Dynamic Reversibility of Water Intrusion into Nanopores: Pressure-Transmitting Fluid with Frequency-Dependent Dissipation Capability

Alexander Lowe, Nikolay Tsyrin, Mirosław Chorążewski, Paweł Zajdel, Michał Mierzwa, Juscelino B. Leão, Markus Bleuel, Tong Feng, Dong Luo, Mian Li, Dan Li, Victor Stoudenets, Sebastian Pawlus, Abdessamad Faik, Yaroslav Grosu

ACS Applied Materials & Interfaces· Volume 11· Issue 43

Abstract

In this article, the effect of a porous material’s flexibility on the dynamic reversibility of a nonwetting liquid intrusion was explored experimentally. For this purpose, high-pressure water intrusion together with high-pressure in situ small-angle neutron scattering were applied for superhydrophobic grafted silica and two metal–organic frameworks (MOFs) with different flexibility [ZIF-8 and Cu2(tebpz) (tebpz = 3,3′,5,5′tetraethyl-4,4′-bipyrazolate)]. These results established the relation between the pressurization rate, water intrusion–extrusion hysteresis, and porous materials’ flexibility. It was demonstrated that the dynamic hysteresis of water intrusion into superhydrophobic nanopores can be controlled by the flexibility of a porous material. This opens a new area of applications for flexible MOFs, namely, a smart pressure-transmitting fluid, capable of dissipating undesired vibrations depending on their frequency. Finally, nanotriboelectric experiments were conducted and the results showed that a porous material’s topology is important for electricity generation while not affecting the dynamic hysteresis at any speed.
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Research context

OpenAlex topics: Nanopore and Nanochannel Transport Studies · Lattice Boltzmann Simulation Studies · NMR spectroscopy and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland

Laboratory of Thermomolecular Energetics, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Pr. Peremogy 37, 03056 Kyiv, Ukraine

Institute of Physics, University of Silesia, 75 Pulku Piechoty 1, 41-500 Chorzow, Poland

Silesian Center for Education and Interdisciplinary Research, University of Silesia, 75 Pulku Piechoty 1A, 41-500 Chorzow, Poland

NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, United States

Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742-2115, United States

Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China

College of Chemistry and Materials Science, Jinan University, 510632 Guangzhou, China

CIC Energigune, Albert Einstein 48, Miñano, Álava 01510, Spain

Funding

National Institute of Standards and Technology

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