journal article·2019-06-05

Nanocage-Based Porous Metal–Organic Frameworks Constructed from Icosahedrons and Tetrahedrons for Selective Gas Adsorption

Da-Shuai Zhang, Yong-Zheng Zhang, Xiuling Zhang, Fei Wang, Jian Zhang, Hui Hu, Jun Gao, Hui Yan, Hui-Ling Liu, Hui-Yan Ma, Long-Long Geng, Yun-Wu Li

ACS Applied Materials & Interfaces· Volume 11· Issue 22
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Abstract

Two isostructural nanocage-based porous Ni/Co(II)-MOFs have been hydrothermally synthesized, which were interestingly composed of icosahedron and tetrahedron cages with a new (3,8)-connected 3D topology. Moreover, the stable Ni-MOF exhibits good selective CO2/CH4 and CO2/N2 adsorption owing to its exposed nitrogen active sites.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, P. R. China

College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266000, P. R. China

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China

College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, P. R. China

Shandong Provincial Key Laboratory/Collaborative Innovation Center of Chemical Energy Storage and Novel Cell Technology, and School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, P. R. China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Shandong Province

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