journal article·2013-06-26

Halochromism of a Polythiophene Derivative Induced by Conformational Changes and Its Sensing Application of Carbon Dioxide

Zhiyi Yao, Xianping Hu, Binghuan Huang, Li Zhang, Lei Liu, Yuliang Zhao, Hai-Chen Wu

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Abstract

We report the design and synthesis of a halochromic polythiophene derivative, whose conformation can be alternated between random coil and rodlike phase by adjusting the pH of the solution. Distinct solution color changes associated with the pH-induced conformational transitions can be used to construct a colorimetric probe for sensing carbon dioxide. This probe can be recovered by bubbling nitrogen gas into carbon dioxide-treated solutions for over 20 cycles.
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Research context

OpenAlex topics: Luminescence and Fluorescent Materials · Polydiacetylene-based materials and applications · Molecular Sensors and Ion Detection

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Biomedical Effects of Nanomaterials & Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450052, China

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