Superhydrophobic Shape Memory Polymer Microarrays with Switchable Directional/Antidirectional Droplet Sliding and Optical Performance

Bioinspired smart surfaces with switchable wettability and optical performance have aroused much attention in the past few years. However, almost all reported surfaces focused on regulating single surface function. In this work, inspired by the butterfly wings, a novel superhydrophobic surface with shape memory polymer microarrays (SMPAs) was prepared through the integration of three-dimensional printing, replica-molding, and a simple surface treatment. In this superhydrophobic SMPA system, the permanent upright microarrays and temporary tilted microarrays can be reversibly switched owing to the excellent shape memory effect (SME). Accompanied by the structure variations, switchable directional/antidirectional droplet sliding and vivid color conversion as the butterfly wings can be achieved. Moreover, because of the SME, local structure regulation can also be achieved on the surface, and with the help of such an ability, the SMPA was further applied as a multifunctional platform to demonstrate controllable droplet transportation and information storage. This work reports the reversible control of directional/antidirectional droplet sliding and tunable color on a superhydrophobic SMPA, and it is believed that such a smart surface can be potentially applied in many fields, such as microfluidic devices and smart optical chips.