Feasible Modification of PEDOT:PSS by Poly(4-styrenesulfonic acid): A Universal Method to Double the Efficiencies for Solution-Processed Organic Light-Emitting Devices

A feasible, universal, and low-cost strategy for solution-processed organic light-emitting diodes (OLEDs) was provided to significantly enhance the electroluminescent performances. The commercially available poly(4-styrenesulfonic acid) (PSSA) aqueous solution was mixed into poly(styrene sulfonic acid)-doped poly(3,4-ethylenedioxythiphene) (PEDOT:PSS) to modify its chemical and physical properties. The corresponding work function can be easily elevated from 5.04 to 5.63 eV. The modification of PEDOT:PSS by PSSA is found to be a universal method to demonstrate highly efficient OLEDs with different solution-processed host/emitter combinations, covering phosphorescent and thermally activated delayed fluorescence devices. The benchmarking solution-processed OLEDs based on 2,4,5,6-tetrakis(carbazol-9-yl)-1,3-dicyanobenzene and bis[2-(4,6-difluorophenyl)pyridinato-C2,N](picolinato)iridium(III) achieved the maximum external quantum efficiencies of 26.6 and 22.4%, respectively, simply by modifying PEDOT:PSS with PSSA, corresponding to the improvement factors of 2.7 and 2.2. It is confirmed that such performances originate simultaneously from reduced interfacial fluorescence quenching, elevated work function, and reduced lateral conduction of the commonly used PEDOT:PSS (Clevios P VP Al 4083).