journal article·2021-07-07

Carbon Fibers Enhance the Propagation of High Loading Nanothermites: In Situ Observation of Microscopic Combustion

Haiyang Wang, Dylan J. Kline, Miles C. Rehwoldt, Michael R. Zachariah

ACS Applied Materials & Interfaces· Volume 13· Issue 26
Publisher page

Abstract

A major challenge in formulating and manufacturing energetic materials lies in the balance between total energy density, energy release rate, and mechanical integrity. In this work, carbon fibers are embedded into ∼90 wt % loading Al/CuO nanothermite sticks through a simple extrusion direct writing technique. With only ∼2.5 wt % carbon fiber addition, the burn rate and heat flux were promoted >2×. In situ microscopic observation of combustion shows that the carbon fiber intercept ejected hot agglomerates near the burning surface and enhanced heat feedback to the unreacted material. This study outlines how these approaches may enhance the propagation and reduce the two-phase flow losses.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Energetic Materials and Combustion · Rocket and propulsion systems research · Thermal and Kinetic Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical and Environmental Engineering, The University of California Riverside, Riverside, California 92521, United States

Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, United States

Funding

Air Force Office of Scientific Research

References (65)

Show source-provided references
1. 10.1002/adma.20160137110.1002/adma.201601371 ↗
2. 10.1016/S0360-1285(97)00015-410.1016/S0360-1285(97)00015-4 ↗
3. 10.1016/j.jhazmat.2004.04.00310.1016/j.jhazmat.2004.04.003 ↗
4. 10.1002/adma.20200129110.1002/adma.202001291 ↗
5. 10.1007/BF0204489710.1007/BF02044897 ↗
6. 10.2514/1.3643610.2514/1.36436 ↗
7. 10.1016/j.powtec.2013.03.01710.1016/j.powtec.2013.03.017 ↗
8. 10.1007/s10853-020-05031-510.1007/s10853-020-05031-5 ↗
9. 10.1016/j.pecs.2017.02.00210.1016/j.pecs.2017.02.002 ↗
10. 10.1002/adem.20190120410.1002/adem.201901204 ↗
11. 10.1088/1361-6528/ab7c4310.1088/1361-6528/ab7c43 ↗
12. 10.1016/j.combustflame.2020.07.00610.1016/j.combustflame.2020.07.006 ↗
13. 10.1021/acsanm.8b0093910.1021/acsanm.8b00939 ↗
14. 10.1016/j.combustflame.2011.02.00410.1016/j.combustflame.2011.02.004 ↗
15. 10.1063/1.493813910.1063/1.4938139 ↗
16. 10.1002/prep.20180009510.1002/prep.201800095 ↗
17. 10.1080/00102202.2020.180488510.1080/00102202.2020.1804885 ↗
18. 10.1016/j.combustflame.2020.07.02310.1016/j.combustflame.2020.07.023 ↗
19. 10.1016/j.combustflame.2020.07.00410.1016/j.combustflame.2020.07.004 ↗
20. 10.1016/j.fuel.2019.11564610.1016/j.fuel.2019.115646 ↗
21. 10.1002/prep.20190038710.1002/prep.201900387 ↗
22. 10.1016/j.combustflame.2018.12.03110.1016/j.combustflame.2018.12.031 ↗
23. 10.1016/j.cej.2017.02.00910.1016/j.cej.2017.02.009 ↗
24. 10.1016/j.proci.2018.06.00310.1016/j.proci.2018.06.003 ↗
25. 10.1016/j.combustflame.2017.04.00710.1016/j.combustflame.2017.04.007 ↗
26. 10.1016/j.combustflame.2020.06.01110.1016/j.combustflame.2020.06.011 ↗
27. 10.1021/acsapm.9b0001610.1021/acsapm.9b00016 ↗
28. 10.1016/j.combustflame.2019.08.02310.1016/j.combustflame.2019.08.023 ↗
29. 10.1016/j.proci.2018.05.05210.1016/j.proci.2018.05.052 ↗
30. 10.1002/prep.20190028110.1002/prep.201900281 ↗
31. 10.1016/j.combustflame.2019.12.00910.1016/j.combustflame.2019.12.009 ↗
32. 10.1002/(SICI)1097-4628(19980222)67:8<1457::AID-APP11>3.0.CO;2-Z10.1002/(SICI)1097-4628(19980222)67:8<1457::AID-APP11>3.0.CO;2-Z ↗
33. 10.1002/adem.20140015110.1002/adem.201400151 ↗
34. 10.1016/j.combustflame.2020.01.02110.1016/j.combustflame.2020.01.021 ↗
35. 10.1021/acsomega.9b0190910.1021/acsomega.9b01909 ↗
36. 10.1016/j.combustflame.2019.10.01710.1016/j.combustflame.2019.10.017 ↗
37. 10.1002/adem.20170039010.1002/adem.201700390 ↗
38. 10.2514/1.B3792310.2514/1.B37923 ↗
39. 10.1016/j.combustflame.2020.06.03710.1016/j.combustflame.2020.06.037 ↗
40. 10.2514/3.5105610.2514/3.51056 ↗
41. 10.1016/j.proci.2016.06.14110.1016/j.proci.2016.06.141 ↗
42. 10.1016/j.combustflame.2021.11149210.1016/j.combustflame.2021.111492 ↗
43. 10.1002/adem.20190014710.1002/adem.201900147 ↗
44. 10.1002/prep.20180018810.1002/prep.201800188 ↗
45. 10.1002/adma.20180657510.1002/adma.201806575 ↗
46. Wang H. · Environmental and Chemical Engineering · 2021
47. 10.1016/j.ces.2020.11608710.1016/j.ces.2020.116087 ↗
48. 10.1038/srep4340110.1038/srep43401 ↗
49. 10.1016/j.jmatprotec.2016.07.02510.1016/j.jmatprotec.2016.07.025 ↗
50. 10.1557/jmr.2014.21210.1557/jmr.2014.212 ↗
51. 10.1016/j.compscitech.2014.10.00910.1016/j.compscitech.2014.10.009 ↗
52. 10.1016/j.cej.2020.12425410.1016/j.cej.2020.124254 ↗
53. 10.1021/jp101473710.1021/jp1014737 ↗
54. 10.1002/adma.20190714210.1002/adma.201907142 ↗
55. 10.1063/1.502189010.1063/1.5021890 ↗
56. 10.1016/j.combustflame.2020.01.02010.1016/j.combustflame.2020.01.020 ↗
57. 10.1016/j.combustflame.2013.10.01710.1016/j.combustflame.2013.10.017 ↗
58. 10.1016/j.combustflame.2017.04.01610.1016/j.combustflame.2017.04.016 ↗
59. 10.1016/j.combustflame.2004.04.00110.1016/j.combustflame.2004.04.001 ↗
60. Lengellé G. · 2002 · 1
61. 10.1002/prep.20180025710.1002/prep.201800257 ↗
62. 10.1016/j.carbon.2008.11.01510.1016/j.carbon.2008.11.015 ↗
63. 10.1016/j.applthermaleng.2008.03.00410.1016/j.applthermaleng.2008.03.004 ↗
64. 10.1016/j.compositesa.2011.11.02410.1016/j.compositesa.2011.11.024 ↗
65. 10.1002/pen.76016090510.1002/pen.760160905 ↗