journal article·2016-02-17

ZIF-8 Cooperating in TiN/Ti/Si Nanorods as Efficient Anodes in Micro-Lithium-Ion-Batteries

Yingjian Yu, Chuang Yue, Xionggui Lin, Shibo Sun, Jinping Gu, Xu He, Chuanhui Zhang, Wei Lin, Donghai Lin, Xinli Liao, Binbin Xu, Suntao Wu, Mingsen Zheng, Jing Li, Junyong Kang, Liwei Lin

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Abstract

Zeolite imidazolate framework-8 (ZIF-8) nanoparticles embedded in TiN/Ti/Si nanorod (NR) arrays without pyrolysis have shown increased energy storage capacity as anodes for lithium ion batteries (LIBs). A high capacity of 1650 μAh cm(-2) has been achieved in this ZIF-8 composited multilayered electrode, which is ∼100 times higher than the plain electrodes made of only silicon NR. According to the electrochemical impedance spectroscopy (EIS) and (1)H nuclear magnetic resonance (NMR) characterizations, the improved diffusion of lithium ions in ZIF-8 and boosted electron/Li(+) transfer by the ZIF-8/TiN/Ti multilayer coating are proposed to be responsible for the enhanced energy storage ability. The first-principles calculations further indicate the favorable accessibility of lithium with appropriate size to diffuse in the open pores of ZIF-8. This work broadens the application of ZIF-8 to silicon-based LIBs electrodes without the pyrolysis and provides design guidelines for other metal-organic frameworks/Si composite electrodes.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Collaborative Innovation Center for Optoelectronic Semiconductors and Efficient Devices, Department of Physics/Pen-Tung Sah Institute of Micro-Nano Science and Technology, Xiamen University, Xiamen, Fujian 361005, China

State Key Laboratory for Manufacturing Systems Engineering, Xi’an Jiaotong University, Xi’an, Shanxi 710049, China

State Key Lab of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China

High-field NMR Research Center, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China

Department of Mechanical Engineering, University of California, Berkeley, California 94720, United States

Funding

Ministry of Science and Technology of the People's Republic of China · China Scholarship Council · State Key Laboratory for Manufacturing Systems Engineering, Xi?an Jiaotong University · Fujian Province

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