journal article·2013-11-13Open access

Gallium-Doped Tin Oxide Nano-Cuboids for Improved Dye Sensitized Solar Cell

Jun Jie Teh, Siong Luong Ting, Kam Chew Leong, Jun Li, Peng Chen

Abstract

Tin dioxide (SnO2) is a potential candidate to replace conventional titanium dioxide (TiO2) in dye-sensitized solar cells (DSSCs) because of its wider bandgap and higher electron mobility. However, SnO2 suffers from low band edge that causes severe backflow of electrons towards electrolyte (charge recombination). Herein, we demonstrate that gallium (Ga) doping can increase the band edge of SnO2, and we show that DSSCs using a Ga-doped SnO2 nano-cuboids based photoanode offer improved open circuit potential (~0.74 V), fill factor (~73.7%), and power conversion efficiency (~4.05%).
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Gas Sensing Nanomaterials and Sensors · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457, Singapore

GlobalFoundries Singapore, 60 Woodlands Industrial Park D Street 2, Singapore 738406, Singapore

Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602, Singapore

References (47)

Show source-provided references
1. Guai G. H. · Adv. Energy Mater. · 2012 · 2 · 33410.1002/aenm.201100582 ↗
2. Guai G. H. · ChemPhysChem · 2012 · 13 · 256610.1002/cphc.201200156 ↗
3. O’Regan B. · Nature · 1991 · 353 · 73710.1038/353737a0 ↗
4. Wang W. · Adv. Funct. Mater. · 2012 · 22 · 277510.1002/adfm.201200168 ↗
5. Yella A. · Science · 2011 · 334 · 62910.1126/science.1209688 ↗
6. Greijer Agrell H. · Sol. Energy · 2003 · 75 · 16910.1016/S0038-092X(03)00248-2 ↗
7. Arnold M. S. · J. Phys. Chem. B · 2002 · 107 · 65910.1021/jp0271054 ↗
8. Teh J. J. · J. Renewable Sustainable Energy · 2013 · 5 · 02312010.1063/1.4798316 ↗
9. Green A. N. M. · J. Phys. Chem. B · 2005 · 109 · 1252510.1021/jp050145y ↗
10. Chappel S. · Sol. Energy Mater. Sol. Cells · 2002 · 71 · 14110.1016/S0927-0248(01)00050-2 ↗
11. Fukai Y. · Electrochem. Commun. · 2007 · 9 · 143910.1016/j.elecom.2007.01.054 ↗
12. Nang Dinh N. · C. R. Chim. · 2006 · 9 · 67610.1016/j.crci.2005.02.042 ↗
13. Zhu K. · Nano Lett. · 2006 · 7 · 6910.1021/nl062000o ↗
14. Ramasamy E. · J. Phys. Chem. C · 2010 · 114 · 2203210.1021/jp1074797 ↗
15. Park N. G. · Langmuir · 2004 · 20 · 424610.1021/la036122x ↗
16. Kim M.-H · J. Phys. Chem. C · 2009 · 113 · 1717610.1021/jp904206a ↗
17. Kim M.-H · J. Phys. Chem. C · 2011 · 115 · 2312010.1021/jp2069978 ↗
18. Pang H. · ACS Appl. Mater. Interfaces · 2012 · 4 · 626110.1021/am3018493 ↗
19. Shang G. · J. Phys. Chem. C · 2013 · 117 · 434510.1021/jp309193n ↗
20. Kim D. W. · Nanoscale · 2012 · 4 · 55710.1039/C1NR11063B ↗
21. Chen J. · J. Phys. Chem. C · 2012 · 116 · 1084110.1021/jp301770n ↗
22. Li Z. · Nanoscale · 2012 · 4 · 349010.1039/c2nr30279a ↗
23. Li Y. · Chem.—Eur. J. · 2012 · 18 · 1171610.1002/chem.201201047 ↗
24. Zhang Y. · J. Phys. Chem. C · 2008 · 112 · 855310.1021/jp800988y ↗
25. Shin S. S. · ACS Nano · 2013 · 7 · 102710.1021/nn305341x ↗
26. Ito S. · Prog. Photovoltaics · 2007 · 15 · 60310.1002/pip.768 ↗
27. Ramasamy E. · Energy Environ. Sci. · 2011 · 4 · 252910.1039/c1ee01123e ↗
28. Dou X. · Chem. Mater. · 2011 · 23 · 393810.1021/cm201366z ↗
29. Dobler D. · Anal. Bioanal. Chem. · 2002 · 374 · 64610.1007/s00216-002-1448-y ↗
30. Yang J. · J. Mater. Chem. · 2009 · 19 · 29210.1039/B807539E ↗
31. Chang S. T. · J. Cryst. Growth · 2004 · 273 · 19510.1016/j.jcrysgro.2004.07.087 ↗
32. Sun S. · Chem.—Eur. J. · 2007 · 13 · 908710.1002/chem.200700448 ↗
33. Szuber J. · Thin Solid Films · 2001 · 391 · 19810.1016/S0040-6090(01)00982-8 ↗
34. Azároff, L. V.Elements of X-ray crystallography;McGraw-Hill:New York, 1968; pp552.
35. Radecka M. · J. Power Sources · 2008 · 181 · 4610.1016/j.jpowsour.2007.10.082 ↗
36. Bandara J. · Thin Solid Films · 2008 · 517 · 95210.1016/j.tsf.2008.07.031 ↗
37. Parks G. A. · Chem. Rev. · 1965 · 65 · 17710.1021/cr60234a002 ↗
38. Xiang P. · Nanoscale Res. Lett. · 2011 · 6 · 60610.1186/1556-276X-6-606 ↗
39. Onwona-Agyeman B. · Jpn. J. Appl. Phys. · 2005 · 44 · 73110.1143/JJAP.44.L731 ↗
40. Ariyasinghe Y. P. Y. P. · J. Photochem. Photobiol., A · 2011 · 217 · 24910.1016/j.jphotochem.2010.10.017 ↗
41. O’Regan B. C. · J. Am. Chem. Soc. · 2008 · 130 · 290610.1021/ja078045o ↗
42. Splan K. E. · J. Phys. Chem. B · 2004 · 108 · 411110.1021/jp037230v ↗
43. Lee S. · J. Phys. Chem. C · 2009 · 113 · 687810.1021/jp9002017 ↗
44. Fuke N. · Chem. Mater. · 2008 · 20 · 497410.1021/cm800797v ↗
45. Papageorgiou N. · J. Electrochem. Soc. · 1997 · 144 · 87610.1149/1.1837502 ↗
46. Wang Q. · J. Phys. Chem. B · 2005 · 109 · 1494510.1021/jp052768h ↗
47. Archana P. S. · J. Phys. Chem. C · 2009 · 113 · 2153810.1021/jp908238q ↗