journal article·2014-08-13

Large-Area Ordered P-type Si Nanowire Arrays as Photocathode for Highly Efficient Photoelectrochemical Hydrogen Generation

Shufan Huang, Haifeng Zhang, Zilong Wu, Dezi Kong, Dongdong Lin, Yongliang Fan, Xinju Yang, Zhenyang Zhong, Shihua Huang, Zuimin Jiang, Chuanwei Cheng

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Abstract

In this Article, we report the successful fabrication of large-area ordered Si nanowire arrays (NWAs) by a cost-effective and scalable wet-etching process in combination with nanospheres lithography technique. The periodical Si NWAs are further investigated as photocathode for water splitting, with excellent hydrogen evolution performances with a maximum photocurrent density of 27 mA cm(-2) achieved, which is ∼2.5 times that of planar Si and random Si nanowires electrode. The greatly improved PEC performance can be attributed to the patterned and ordered NWs structure as a result of enhancement of the light harvesting as well as charge transportation and collection efficiency.
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Research context

OpenAlex topics: Nanowire Synthesis and Applications · Ga2O3 and related materials · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Surface Physics, Key Laboratory of Micro and Nano Photonic Structures (Ministry of Education) and Department of Physics, Fudan University, Shanghai 200433, People’s Republic of China

MOE Key Laboratory of Advanced Micro-structured Materials, School of Physics Science and Engineering, Tongji University, Shanghai 200092, People’s Republic of China

Department of Material Physics, Zhejiang Normal University, Jinhua 321004, People’s Republic of China

Funding

National Natural Science Foundation of China

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