Class of Solid-like Electrolytes for Rechargeable Batteries Based on Metal–Organic Frameworks Infiltrated with Liquid Electrolytes
Source abstract
Abstract
A new family of solid-like electrolytes was developed by infiltrating MIL-100(Al), an electrochemically stable metal–organic-framework (MOF) material, with liquid electrolytes that contain cations from the 3rd period (Na+, Mg2+, and Al3+) and the 1st group (Li+, Na+, K+, and Cs+). The anions were immobilized within the MOF scaffolds upon complexing with the open metal sites, allowing effective transport of the cations in the nanoporous channels with high conductivity (up to 1 mS cm–1) and low activation energy (down to 0.2 eV). This general approach enables the fabrication of superior conductive solid-like electrolytes beyond lithium ions.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Metal-Organic Frameworks: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, California 90095, United States
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China
Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, P. R. China
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
Funding
University of California, Los Angeles
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