SuFEx in Metal–Organic Frameworks: Versatile Postsynthetic Modification Tool
Source abstract
Abstract
A new type of click reaction, sulfur(VI) fluoride exchange (SuFEx), has been utilized to prepare five postsynthetically modified UiO-67 series metal–organic frameworks (MOFs). The postsynthetic modification (PSM) via SuFEx can be achieved selectively for the sulfonyl fluoride (R-SO2F) without degrading the MOF structure as confirmed by X-ray crystallographic analysis. The present SuFEx method provides a straightforward tool for introducing new functionality inside MOFs. Introduction of an imidazolium group into the MOF afforded a heterogeneous catalyst for the benzoin condensation reaction.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Zeolite Catalysis and Synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Center for Self-Assembly and Complexity, Institute for Basic Science (IBS), Pohang 790-784, Republic of Korea
Department of Chemistry, College of Natural Science, Seoul National University, Seoul 440-746, Republic of Korea
Funding
National Research Foundation of Korea · Institute for Basic Science
References (62)
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