journal article·2017-03-29

Microwave Effects on Co–Pi Cocatalysts Deposited on α-Fe2O3 for Application to Photocatalytic Oxygen Evolution

Masato M. Maitani, Takuya Yamada, Hisanori Mashiko, Kohei Yoshimatsu, Takayoshi Oshima, Akira Ohtomo, Yuji Wada

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Abstract

We analyze the effects of microwave applied in the process of photoelectrochemical deposition of cobalt-based cocatalysts, Co–Pi, onto well-orientated flat α-Fe 2 O 3 thin films, which were fabricated by pulsed laser deposition. As compared with conventional heating, microwave significantly affects the morphology, chemical composition, and photocatalytic activity of Co-Pi/α-Fe 2 O 3 composite. A significant enhancement in photocurrent related to photocatalytic water oxidation is achieved by the Co–Pi catalyst prepared under microwave irradiation. This, along with its interfacial electron-transfer properties, is studied by means of electrochemical impedance spectroscopy.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Nanomaterials for catalytic reactions · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8550, Japan

Funding

New Energy and Industrial Technology Development Organization · Ministry of Education, Culture, Sports, Science and Technology · Japan Society for the Promotion of Science · Tokyo Institute of Technology · JFE 21st Century Foundation · TEPCO Memorial Foundation

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