Tailoring Coral-Like Fe₇Se₈@C for Superior Low-Temperature Li/Na-Ion Half/Full Batteries: Synthesis, Structure, and DFT Studies

The intrinsic charge-transfer property bears the primary responsibility for the sluggish redox kinetics of the common electrode materials, especially operated at low temperatures. Herein, we report the crafting of homogeneously confined Fe₇Se₈ nanoparticles with a well-defined graphitic carbon matrix that demonstrate a highly efficient charge-transfer system in a designed natural coral-like structure (cl-Fe₇Se₈@C). Notably, the intricate architecture as well as highly conductive peculiarity of C concurrently satisfy the demands of achieving fast ionic/electrical conductivities for both Li/Na-ion batteries in a wide temperature range. For example, when cl-Fe₇Se₈@C is employed as the anode material to assemble full batteries with the cathode of Na₃V₂(PO₄)₂O₂F (NVPOF), decent capacities of 323.1 and 175.9 mA h g^-1 can be acquired at temperatures of 25 and -25 °C, respectively. This work is significant for further developing potential anode materials for advanced energy storage and conversion under low-temperature conditions.