DataVXACS Applied Materials & InterfacesPaper
journal article·2017-02-22

Bioinspired Universal Monolayer Coatings by Combining Concepts from Blood Protein Adsorption and Mussel Adhesion

Leixiao Yu, Chong Cheng, Qidi Ran, Christoph Schlaich, Paul-Ludwig Michael Noeske, Wenzhong Li, Qiang Wei, Rainer Haag

ACS Applied Materials & Interfaces· Volume 9· Issue 7
Publisher page
Source abstract

Abstract

Despite the increasing need for universal polymer coating strategies, only a few approaches have been successfully developed, and most of them are suffering from color, high thickness, or high roughness. In this paper, we present for the first time a universal monolayer coating that is only a few nanometers thick and independent of the composition, size, shape, and structure of the substrate. The coating is based on a bioinspired synthetic amphiphilic block copolymer that combines two concepts from blood protein adsorption and mussel adhesion. This polymer can be rapidly tethered on various substrates including both planar surfaces and nanosystems with high grafting density. The resulting monolayer coatings are, on the one hand, inert to the adsorption of multiple polymer layers and prevent biofouling. On the other hand, they are chemically active for secondary functionalization and provide a new platform for selective material surface modification.
Source: openalex_inverted_index · Quality: baseline

Research context

PolymersNanomaterials

OpenAlex topics: Polymer Surface Interaction Studies · Surface Modification and Superhydrophobicity · Nanofabrication and Lithography Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Chemistry and Biochemistry, Freie Universität Berlin, Takustrasse 3, 14195 Berlin, Germany

Multifunctional Biomaterials for Medicine, Helmholtz Virtual Institute, Kantstrasse 55, 14513 Teltow-Seehof, Germany

Soft Matter and Functional Materials, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

Fraunhofer Institute for Manufacturing Technology and Advanced Materials, Wiener Strasse 12, 28359 Bremen, Germany

Department of Biointerface Science & Technology, Max-Planck Institute for Medical Research, Heisenbergstrasse 3, 70569 Stuttgart, Germany

Funding

Chinese Scholar Council (CSC) · Helmholtz Virtual Institute on ?Multifunctional Biomaterials for Medicine?

References (42)

Show source-provided references
1. 10.1021/cr200091610.1021/cr2000916 ↗
2. 10.1039/C5MH00089K10.1039/C5MH00089K ↗
3. 10.1021/cm950369110.1021/cm9503691 ↗
4. 10.1126/science.277.5330.123210.1126/science.277.5330.1232 ↗
5. 10.1002/admi.20160060010.1002/admi.201600600 ↗
6. 10.1002/admi.20140040110.1002/admi.201400401 ↗
7. 10.1126/science.110660410.1126/science.1106604 ↗
8. 10.1002/(SICI)1521-3927(19980901)19:9<441::AID-MARC441>3.0.CO;2-G10.1002/(SICI)1521-3927(19980901)19:9<441::AID-MARC441>3.0.CO;2-G ↗
9. 10.1126/science.114724110.1126/science.1147241 ↗
10. 10.1126/science.123726510.1126/science.1237265 ↗
11. 10.1038/nnano.2014.19910.1038/nnano.2014.199 ↗
12. 10.1021/acs.chemmater.6b0158710.1021/acs.chemmater.6b01587 ↗
13. 10.1002/anie.20130164610.1002/anie.201301646 ↗
14. 10.1002/anie.20140054610.1002/anie.201400546 ↗
15. 10.1146/annurev-matsci-062910-10042910.1146/annurev-matsci-062910-100429 ↗
16. 10.1021/ja309590f10.1021/ja309590f ↗
17. 10.1002/ange.20160188110.1002/ange.201601881 ↗
18. 10.1021/ma802063s10.1021/ma802063s ↗
19. 10.1002/adfm.20100093210.1002/adfm.201000932 ↗
20. 10.1039/c0py00215a10.1039/c0py00215a ↗
21. 10.1002/jbm.82023030610.1002/jbm.820230306 ↗
22. 10.1371/journal.pone.016649010.1371/journal.pone.0166490 ↗
23. 10.1002/anie.20120111410.1002/anie.201201114 ↗
24. 10.1002/anie.20140711310.1002/anie.201407113 ↗
25. 10.1126/science.aab055610.1126/science.aab0556 ↗
26. 10.1038/ncomms973710.1038/ncomms9737 ↗
27. 10.1016/S1369-7021(05)71079-810.1016/S1369-7021(05)71079-8 ↗
28. 10.1021/ja202760x10.1021/ja202760x ↗
29. 10.1073/pnas.95.21.1227110.1073/pnas.95.21.12271 ↗
30. 10.1021/la800345410.1021/la8003454 ↗
31. 10.1002/adma.20130473710.1002/adma.201304737 ↗
32. 10.1016/j.apsusc.2016.05.09710.1016/j.apsusc.2016.05.097 ↗
33. 10.1021/ma101113g10.1021/ma101113g ↗
34. 10.1002/adfm.20160021010.1002/adfm.201600210 ↗
35. 10.1002/chem.20030607310.1002/chem.200306073 ↗
36. Ratner B. D. · J. Dent. Educ. · 2001 · 65 · 134010.1002/j.0022-0337.2001.65.12.tb03493.x ↗
37. 10.1016/S0142-9612(03)00343-010.1016/S0142-9612(03)00343-0 ↗
38. 10.1002/anie.20100376110.1002/anie.201003761 ↗
39. 10.1002/cphc.20030101410.1002/cphc.200301014 ↗
40. 10.3762/bjoc.11.8710.3762/bjoc.11.87 ↗
41. 10.1021/acs.nanolett.5b0225610.1021/acs.nanolett.5b02256 ↗
42. 10.1002/anie.20070019710.1002/anie.200700197 ↗