journal article·2021-10-06

Interfacing with Fe–N–C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles

Shan Zhong, Xinchun Yang, Liyu Chen, Nobuko Tsumori, Noboru Taguchi, Qiang Xu

ACS Applied Materials & Interfaces· Volume 13· Issue 39
Publisher page

Abstract

Hierarchical micro-/mesoporous carbons with abundant Fe–N–C sites were prepared through one-step carbonization of a metal–organic framework (MOF) with sodium iron ethylenediaminetetraacetic acid [NaFe(III)EDTA], which can facilitate the nucleation and growth of ultrafine (∼1.4 nm) and highly dispersed palladium nanoparticles (Pd NPs). Interfacing Pd NPs with Fe–N–C sites has been demonstrated for the first time to boost the heterogeneous catalysis of hydrogen production from formic acid, affording an ultrahigh turnover frequency (TOF) value of 7361 h–1 at 323 K. The robust synergistic interactions between Pd NPs and Fe–N–C sites together with the small size effects of Pd NPs are responsible for the enhanced catalytic activity.
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Research context

OpenAlex topics: Carbon dioxide utilization in catalysis · Metal-Organic Frameworks: Synthesis and Applications · Hydrogen Storage and Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Research Institute of Electrochemical Energy, National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan

Graduate School of Engineering, Kobe University, Kobe, Hyogo 657-8501, Japan

School of Energy and Power Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), National Institute of Advanced Industrial Science and Technology (AIST), and Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan

Department of Applied Chemistry and Chemical Engineering, Toyama National College of Technology, 13 Hongo-machi, Toyama 939-8630, Japan

Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China

Funding

Ministry of Education, Culture, Sports, Science and Technology · National Institute of Advanced Industrial Science and Technology

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