journal article·2017-04-26

Controlled Fabrication of Functional Capsules Based on the Synergistic Interaction between Polyphenols and MOFs under Weak Basic Condition

Hui Wang, Wei Zhu, Yuan Ping, Chen Wang, Ning Gao, Xianpeng Yin, Chen Gu, Dan Ding, C. Jeffrey Brinker, Guangtao Li

Publisher page

Abstract

Metal-organic coordination materials with controllable nanostructures are of widespread interest due to the coupled benefits of inorganic/organic building blocks and desired architectures. In this work, based on the finding of a synergistic interaction between metal-organic frameworks (MOFs) and natural polyphenols under weak basic condition, a facile strategy has been developed for directly fabricating diverse phenolic-inspired functional materials or metal-phenolic frameworks (MPFs) with controlled hollow nanostructures (polyhedral core-shell, rattle-like, hollow cage, etc.) and controllable size, morphology, and roughness, as well as composition. By further incorporating the diverse functionalities of polyphenols such as low toxicity and therapeutic properties, catalytic activity, and ability to serve as carbon precursors, into the novel assemblies, diverse artificially designed nanoarchitectures with target functionalities have been generated for an array of applications.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Dendrimers and Hyperbranched Polymers · Nanoplatforms for cancer theranostics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Lab of Organic Optoelectronic and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 10084, People’s Republic of China

College of Chemical Engineering, Shijiazhuang University, Shijiazhuang 050035, P. R. China

Advanced Materials Laboratory, Sandia National Laboratories, Albuquerque, New Mexico 87185, United States

School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore

School of Pharmaceutical Sciences, Higher Education Mega Center, Sun Yat-Sen University, Panyu, Guangzhou 510006, China

State Key Laboratory of Medicinal Chemical Biology, Nankai University, Tianjin 300071, People’s Republic of China

Funding

Ministry of Science and Technology of the People's Republic of China · Air Force Office of Scientific Research · Deutsche Forschungsgemeinschaft · Laboratory Directed Research and Development · National Natural Science Foundation of China

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