journal article·2018-06-13Open access

Mesoporous Manganese Phosphonate Nanorods as a Prospective Anode for Lithium-Ion Batteries

Peng Mei, Jaewoo Lee, Malay Pramanik, Abdulmohsen Alshehri, Jeonghun Kim, Joel Henzie, Jung Ho Kim, Yusuke Yamauchi

ACS Applied Materials & Interfaces· Volume 10· Issue 23

Abstract

Mesoporous materials can serve as well-performed electrode candidates for lithium-ion batteries (LIBs). Mesoporous manganese phosphonate (MnP) nanorods are composed of an interconnected network of pores that have high infiltration capacity for electrolyte and less tortuous transport pathways for lithium/electron charge carriers. The mesoporous architecture should also help alleviate stress from volume variation upon lithium intercalation/deintercalation cycles. We used MnP as an LIB anode and observed an initial reversible capacity of 420 mA h g–1 and a modest Coulombic efficiency of 68.7% at a relatively high current density of 144 mA g–1. The reversible capacity stabilizes at 253 mA h g–1 after 100 repetitive cycles, while most of the time, the Coulombic efficiency remains around 100%. The results show that, as a prospective LIB anode, the mesoporous MnP can achieve desirable capacity with decent durability and rate capability.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

Department of Nanoscience and Nanoengineering, Faculty of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo 169-8555, Japan

Australian Institute for Innovative Materials (AIIM), University of Wollongong, Squires Way, North Wollongong, New South Wales 2500, Australia

Department of Chemistry, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia

School of Chemical Engineering & Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, Queensland 4072, Australia

Department of Plant & Environmental New Resources, Kyung Hee University, 1732 Deogyeong-daero, Giheunggu, Yongin-si, Gyeonggi-do 446-701, South Korea

Funding

Qingdao University of Science and Technology · Australian Research Council · Japan Society for the Promotion of Science · Suzuken Memorial Foundation

References (67)

Show source-provided references
1. 10.1038/nmat151310.1038/nmat1513 ↗
2. 10.1021/cr020730k10.1021/cr020730k ↗
3. 10.1016/j.rser.2017.05.00110.1016/j.rser.2017.05.001 ↗
4. 10.1038/373557a010.1038/373557a0 ↗
5. 10.1038/3510464410.1038/35104644 ↗
6. 10.1039/c1ee01598b10.1039/c1ee01598b ↗
7. 10.1002/adma.20100071710.1002/adma.201000717 ↗
8. 10.1039/c2ee21892e10.1039/c2ee21892e ↗
9. 10.1002/aenm.20120002810.1002/aenm.201200028 ↗
10. 10.1016/j.nanoen.2013.05.01310.1016/j.nanoen.2013.05.013 ↗
11. 10.1016/j.ssi.2008.01.09510.1016/j.ssi.2008.01.095 ↗
12. 10.1016/j.jpowsour.2013.11.10310.1016/j.jpowsour.2013.11.103 ↗
13. Winter M. · 2004 · 144
14. 10.1016/j.mattod.2014.10.04010.1016/j.mattod.2014.10.040 ↗
15. 10.1002/aenm.20110048510.1002/aenm.201100485 ↗
16. 10.1246/cl.2008.14210.1246/cl.2008.142 ↗
17. 10.1016/j.jpowsour.2012.02.11110.1016/j.jpowsour.2012.02.111 ↗
18. 10.1002/adfm.20160012110.1002/adfm.201600121 ↗
19. 10.1039/b617519h10.1039/b617519h ↗
20. 10.1021/am301123f10.1021/am301123f ↗
21. 10.1002/aenm.20120008710.1002/aenm.201200087 ↗
22. 10.1002/adfm.20120214410.1002/adfm.201202144 ↗
23. 10.1002/anie.20140461510.1002/anie.201404615 ↗
24. 10.1002/anie.20045408010.1002/anie.200454080 ↗
25. 10.1039/c6ta09297g10.1039/c6ta09297g ↗
26. 10.1002/aenm.20120032010.1002/aenm.201200320 ↗
27. 10.1016/j.micromeso.2017.02.05510.1016/j.micromeso.2017.02.055 ↗
28. 10.1002/cssc.20110005010.1002/cssc.201100050 ↗
29. 10.1021/cs501124d10.1021/cs501124d ↗
30. 10.1021/am504554h10.1021/am504554h ↗
31. 10.1021/cm504404510.1021/cm5044045 ↗
32. 10.1021/acsami.6b0101210.1021/acsami.6b01012 ↗
33. 10.1039/c7ta00775b10.1039/c7ta00775b ↗
34. 10.1002/chem.20160415910.1002/chem.201604159 ↗
35. 10.1039/c7ta07034a10.1039/c7ta07034a ↗
36. 10.1016/j.micromeso.2006.10.01510.1016/j.micromeso.2006.10.015 ↗
37. 10.1016/0368-2048(94)02375-110.1016/0368-2048(94)02375-1 ↗
38. 10.1016/0368-2048(75)85010-910.1016/0368-2048(75)85010-9 ↗
39. 10.1016/j.apsusc.2009.11.05110.1016/j.apsusc.2009.11.051 ↗
40. 10.1016/j.apsusc.2015.12.15910.1016/j.apsusc.2015.12.159 ↗
41. 10.1039/b920964f10.1039/b920964f ↗
42. 10.1021/cr300188410.1021/cr3001884 ↗
43. 10.1002/adfm.20160135710.1002/adfm.201601357 ↗
44. 10.1021/ic301579g10.1021/ic301579g ↗
45. Balaya, P.; Saravanan, K.; Hariharan, S.; Ramar, V.; Lee, H. S.; Kuezma, M.; Devaraj, S.; Nagaraju, D. H.; Ananthanarayanan, K.; Mason, C. W. Nanostructured Mesoporous Materials for Lithium-Ion Battery Applications. Energy Harvesting and Storage: Materials, Devices, and Applications II, 2011; Vol. 8035, pp 1–13.10.1117/12.884460 ↗
46. 10.1039/c0jm03132a10.1039/c0jm03132a ↗
47. 10.1039/c2cs35322a10.1039/c2cs35322a ↗
48. 10.1039/c2cs35086f10.1039/c2cs35086f ↗
49. 10.1002/anie.20070250510.1002/anie.200702505 ↗
50. 10.1002/anie.20050166310.1002/anie.200501663 ↗
51. 10.1166/jnn.2016.1288310.1166/jnn.2016.12883 ↗
52. 10.1016/j.micromeso.2011.09.03210.1016/j.micromeso.2011.09.032 ↗
53. 10.1021/cm071418010.1021/cm0714180 ↗
54. 10.1002/adma.20060249910.1002/adma.200602499 ↗
55. 10.1007/s10008005017310.1007/s100080050173 ↗
56. 10.1016/j.jpowsour.2005.01.00610.1016/j.jpowsour.2005.01.006 ↗
57. 10.1149/1.183834910.1149/1.1838349 ↗
58. 10.1016/j.jpowsour.2017.03.04210.1016/j.jpowsour.2017.03.042 ↗
59. 10.1016/s1388-2481(99)00123-x10.1016/s1388-2481(99)00123-x ↗
60. 10.1016/j.electacta.2003.10.01610.1016/j.electacta.2003.10.016 ↗
61. 10.1149/1.139175910.1149/1.1391759 ↗
62. 10.1016/s0013-4686(99)00194-210.1016/s0013-4686(99)00194-2 ↗
63. 10.1016/j.jpowsour.2010.12.10210.1016/j.jpowsour.2010.12.102 ↗
64. 10.1016/j.jallcom.2012.01.14310.1016/j.jallcom.2012.01.143 ↗
65. 10.1016/s0013-4686(02)00017-810.1016/s0013-4686(02)00017-8 ↗
66. 10.1016/j.matlet.2011.07.02710.1016/j.matlet.2011.07.027 ↗
67. 10.1063/1.183599510.1063/1.1835995 ↗