journal article·2017-10-04

Synthesis-Free Phase-Selective Gelator for Oil-Spill Remediation

Yaowen Cui, Mei-Chun Li, Qinglin Wu, John A. Pojman, Daniel G. Kuroda

Publisher page

Abstract

A new deep eutectic solvent (DES) was developed as a phase-selective gelator for oil-spill remediation. The newly designed nonionic DES is based on a combination of an amide (N-methylacetamide) and a long chain carboxylic acid (lauric acid) and does not require any synthetic procedure besides mixing. Our studies show that the DES works as gelator by forming a gel between lauric acid and the hydrocarbon, whereas the amide serves to form the DES and dissolves in water during the gelation process. In addition, the DES material has gelation properties comparable to those considered as state-of-the-art. Overall, the newly developed material shows a promising future in oil recovery methodologies.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Supramolecular Self-Assembly in Materials · Metal-Organic Frameworks: Synthesis and Applications · Ionic liquids properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, United States

School of Renewable Natural Resources, Louisiana State University Agricultural Center, Baton Rouge, Louisiana 70803, United States

Funding

Louisiana Board of Regents · Department of Chemistry, Louisiana State University

References (29)

Show source-provided references
1. Fingas M. · 201210.1201/b13686 ↗
2. 10.1016/j.tet.2009.02.05610.1016/j.tet.2009.02.056 ↗
3. 10.1002/anie.20100209510.1002/anie.201002095 ↗
4. 10.1002/anie.20151030810.1002/anie.201510308 ↗
5. 10.1039/C4CC06024E10.1039/C4CC06024E ↗
6. 10.1039/c2cc31631e10.1039/c2cc31631e ↗
7. 10.1039/c2jm30711a10.1039/c2jm30711a ↗
8. 10.1021/acs.chemmater.6b0136710.1021/acs.chemmater.6b01367 ↗
9. 10.1002/cplu.20140212010.1002/cplu.201402120 ↗
10. 10.1039/b007848o10.1039/b007848o ↗
11. 10.1002/anie.20161185210.1002/anie.201611852 ↗
12. 10.1016/j.tet.2009.02.05610.1016/j.tet.2009.02.056 ↗
13. 10.1038/pj.2014.6410.1038/pj.2014.64 ↗
14. 10.1039/c2cs15353j10.1039/c2cs15353j ↗
15. 10.1021/ef502887310.1021/ef5028873 ↗
16. 10.1021/cr300162p10.1021/cr300162p ↗
17. 10.1039/c2cs35178a10.1039/c2cs35178a ↗
18. 10.1039/b210714g10.1039/b210714g ↗
19. 10.1016/j.apsusc.2011.05.10610.1016/j.apsusc.2011.05.106 ↗
20. 10.1016/j.jelechem.2011.04.01510.1016/j.jelechem.2011.04.015 ↗
21. 10.1039/b923589b10.1039/b923589b ↗
22. 10.1021/je700638u10.1021/je700638u ↗
23. 10.1021/ef200494310.1021/ef2004943 ↗
24. 10.1016/j.electacta.2013.03.15010.1016/j.electacta.2013.03.150 ↗
25. 10.1016/j.molliq.2016.06.10610.1016/j.molliq.2016.06.106 ↗
26. 10.1016/j.ijpharm.2009.05.03910.1016/j.ijpharm.2009.05.039 ↗
27. SIGMA-ALDRICH Lauric acid; W261408. http://www.sigmaaldrich.com(accessed May 2017) .
28. ACROS-ORGANICS N-methylacetamide; AC126140000. http://www.acros.com(accessed May 2017) .
29. 10.1021/jp906072w10.1021/jp906072w ↗