journal article·2014-12-24

Nanostructured Proton Conductors Formed via in Situ Polymerization of Ionic Liquid Crystals

Fei Lu, Xinpei Gao, Bin Dong, Panpan Sun, Nan Sun, Shuting Xie, Liqiang Zheng

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Abstract

Ionic liquid crystals (ILCs) with hexagonal and lamellar phases were successfully fabricated by the self-assembly of a polymerizable amphiphilic zwitterion, which is formed by 3-(1-vinyl-3-imidazolio)propanesulfonate (VIPS) and 4-dodecyl benzenesulfonic acid (DBSA) based on intermolecular electrostatic interactions. The microstructures and phase behaviors of ILCs were studied by polarized microscope (POM) and small-angle X-ray scattering (SAXS). The ILC topological structures can be considered as proton pathways and further fixed by photopolymerization to prepare nanostructured proton-conductive films. The introduction of highly ordered and well-defined ILC structures into these polymeric films radically improves the ionic conductivities.
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Research context

OpenAlex topics: Ionic liquids properties and applications · Conducting polymers and applications · Analytical Chemistry and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, China

China Ionic Liquid Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China

Funding

National Natural Science Foundation of China · Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · Natural Science Foundation of Shandong Province

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