Electrochemically Enabled Embedded Three-Dimensional Printing of Freestanding Gallium Wire-like Structures

The ability to pattern planar and freestanding 3D metallic architectures would enable numerous applications, including flexible electronics, displays, sensors, and antennas. Low melting point metals, such as gallium, have recently drawn considerable attention especially in the fields of flexible and stretchable electronics and devices owing to its unique properties, such as excellent electrical conductivity and fluidity. However, the large surface tension, low viscosity, and large density pose great challenges to 3D printing of freestanding gallium structures in a large scale, which hinder its further applications. In this article, we first propose an electrochemically enabled embedded 3D printing (3e-3DP) method for creating planar and freestanding gallium wire-like structures assisted with supporting hydrogel. After an enhanced solidification process and the removal of hydrogel, various freestanding 2D and 3D wire-like structures are realized. By simply reassembling the gallium structure into soft elastomer, a gallium-based flexible conductor and a 3D-spiral pressure sensor are demonstrated. Above all, this study presents a brand-new and economical way for the fabrication of 2D and 3D freestanding gallium structures, which has great prospects in wide applications in flexible and stretchable electronics and devices.