journal article·2019-03-13

Nano- to Micro-Self-Aggregates of New Bisimidazole-Based Copoly(ionic liquid)s for Protecting Copper in Aqueous Sulfuric Acid Solution

Haijun Huang, Yan Fu, Xinchao Wang, Yichun Gao, Zhenqiang Wang, Shengtao Zhang, Hongru Li, Fang Gao, Lingyun Chen

ACS Applied Materials & Interfaces· Volume 11· Issue 10
Publisher page

Abstract

This study presents the synthesis of two new bisimidazole-based copoly(ionic liquid)s (PILs) through multistep preparation routes. It is shown that the target PILs can display orderly molecular stacking, and nano- to micro-self-aggregates are yielded in aqueous sulfuric acid solution, which are characterized by various technologies including scanning electron microscopy, transmission electron microscopy, and dynamic light scattering. The studied PIL aggregates show strong chemical adsorption onto the copper surfaces demonstrated by Fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. Furthermore, the anticorrosion performance of the studied PIL aggregates is shown using polarization curves and impedance spectroscopy. As a result, the target PIL aggregates show great corrosion inhibition performance to protect copper in aggressive acid medium.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Ionic liquids properties and applications · Electrochemical Analysis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemistry and Chemical Engineering, Chongqing University, Chongqing, China 400044

College of Pharmacy, Heze University, Heze, Shandong, China 274000

The Eighth Middle-School, Shapingba District, Chongqing, China 400030

College of Chemistry, Chongqing Normal University, Chongqing, China 401331

Funding

Chongqing University · Chongqing Science and Technology Commission · China Postdoctoral Science Foundation · National Natural Science Foundation of China

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