journal article·2016-07-13

Dodecahedron-Shaped Porous Vanadium Oxide and Carbon Composite for High-Rate Lithium Ion Batteries

Yifang Zhang, Anqiang Pan, Yaping Wang, Weifeng Wei, Yanhui Su, Jimei Hu, Guozhong Cao, Shuquan Liang

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Abstract

Carbon-based nanocomposites have been extensively studied in energy storage and conversion systems because of their superior electrochemical performance. However, the majority of metal oxides are grown on the surface of carbonaceous material. Herein, we report a different strategy of constructing V2O5 within the metal organic framework derived carbonaceous dodecahedrons. Vanadium precursor is absorbed into the porous dodecahedron-shaped carbon framework first and then in situ converted into V2O5 within the carbonaceous framework in the annealing process in air. As cathode materials for lithium ion batteries, the porous V2O5@C composites exhibit enhanced electrochemical performance, due to the synergistic effect of V2O5 and carbon composite.
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Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science & Engineering, Central South University, Changsha 410083, Hunan, China

State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, Hunan, China

Department of Materials Science & Engineering, University of Washington, Seattle, Washington 98195, United States

Funding

Program for New Century Excellent Talents in University · Ministry of Education of the People's Republic of China · Natural Science Foundation of?Hunan Province · National Natural Science Foundation of China

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