journal article·2015-06-03

Highly Active Hydrogen Evolution Electrodes via Co-Deposition of Platinum and Polyoxometalates

Chao Zhang, Yahui Hong, Ruihan Dai, Xinping Lin, La-Sheng Long, Cheng Wang, Wenbin Lin

Publisher page

Abstract

A highly active hydrogen evolution reaction (HER) electrode with low Pt loading on glassy carbon (GC) has been prepared by anodic platinum dissolution and co-deposition of polyoxometalates. TEM, EDS, XPS, CV, and ICP-MS analyses gave a Pt loading of 50-100 ng/cm2, corresponding to a Pt coverage of only 0.08-0.16 monolayer. With an overpotential of 65 mV at 20 mA/cm2, the modified GC has a HER activity comparable to that of the commercial Pt working electrode.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Polyoxometalates: Synthesis and Applications · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China

Department of Chemistry, University of Chicago, 929 E 57th Street, Chicago, Illinois 60637, United States

Funding

Division of Materials Research · Central People's Government of the People's Republic of China

References (51)

Show source-provided references
1. Turner J. A. · Science · 2004 · 305 · 97210.1126/science.1103197 ↗
2. Ogden J. M. · Annu. Rev. Energy · 1999 · 24 · 22710.1146/annurev.energy.24.1.227 ↗
3. Carmo M. · Int. J. Hydrogen Energy · 2013 · 38 · 490110.1016/j.ijhydene.2013.01.151 ↗
4. Nocera D. G. · Acc. Chem. Res. · 2012 · 45 · 76710.1021/ar2003013 ↗
5. Gray H. B. · Nat. Chem. · 2009 · 1 · 11210.1038/nchem.206 ↗
6. Walter M. G. · Chem. Rev. · 2010 · 110 · 644610.1021/cr1002326 ↗
7. Merki D. · Energy Environ. Sci. · 2011 · 4 · 387810.1039/c1ee01970h ↗
8. Yuhas B. D. · J. Am. Chem. Soc. · 2012 · 134 · 1035310.1021/ja303640s ↗
9. Shim Y. · J. Am. Chem. Soc. · 2014 · 136 · 1337110.1021/ja507297p ↗
10. Curtin P. N. · Inorg. Chem. · 2009 · 48 · 1049810.1021/ic9007763 ↗
11. Sartorel A. · J. Am. Chem. Soc. · 2008 · 130 · 500610.1021/ja077837f ↗
12. Tinker L. L. · Inorg. Chem. · 2009 · 48 · 1050710.1021/ic900777g ↗
13. Garand E. · Science · 2012 · 335 · 69410.1126/science.1214948 ↗
14. Sun Y. · J. Am. Chem. Soc. · 2013 · 135 · 1769910.1021/ja4094764 ↗
15. Yang L. · Nanoscale · 2015 · 7 · 520310.1039/C4NR06754A ↗
16. Morales-Guio C. G. · Chem. Soc. Rev. · 2014 · 43 · 655510.1039/C3CS60468C ↗
17. Popczun E. J. · Angew. Chem., Int. Ed. · 2014 · 53 · 542710.1002/anie.201402646 ↗
18. Vrubel H. · Energy Environ. Sci. · 2012 · 5 · 613610.1039/c2ee02835b ↗
19. Vrubel H. · Angew. Chem., Int. Ed. · 2012 · 51 · 1270310.1002/anie.201207111 ↗
20. deKrafft K. E. · Adv. Mater. · 2012 · 24 · 201410.1002/adma.201200330 ↗
21. Esposito D. V. · Energy Environ. Sci. · 2011 · 4 · 390010.1039/c1ee01851e ↗
22. Esposito D. V. · Angew. Chem., Int. Ed. · 2010 · 49 · 985910.1002/anie.201004718 ↗
23. Esposito D. V. · J. Am. Chem. Soc. · 2012 · 134 · 302510.1021/ja208656v ↗
24. Gordon R. B. · Proc. Natl. Acad. Sci. U.S.A. · 2006 · 103 · 120910.1073/pnas.0509498103 ↗
25. Levy R. B. · Science · 1973 · 181 · 54710.1126/science.181.4099.547 ↗
26. Carmo M. · Int. J. Hydrogen Energy · 2013 · 38 · 490110.1016/j.ijhydene.2013.01.151 ↗
27. Cook T. R. · Chem. Rev. · 2010 · 110 · 647410.1021/cr100246c ↗
28. Smith R. D. L. · Science · 2013 · 340 · 6010.1126/science.1233638 ↗
29. Bhowmick R. · J. Am. Chem. Soc. · 2011 · 133 · 558010.1021/ja200403m ↗
30. Fu Q. · Science · 2010 · 328 · 114110.1126/science.1188267 ↗
31. Hu P. · Langmuir · 2015 · 31 · 52210.1021/la503995c ↗
32. Lu X. · Nat. Commun. · 2015 · 6
33. Keïta B. · J. Electroanal. Chem. Interfacial Electrochem. · 1985 · 191 · 441
34. Keita B. · Mater. Chem. Phys. · 1989 · 22 · 7710.1016/0254-0584(89)90032-1 ↗
35. Kulesza P. J. · J. Am. Chem. Soc. · 1988 · 110 · 490510.1021/ja00223a006 ↗
36. Kulesza P. J. · J. Electroanal. Chem. Interfacial Electrochem. · 1988 · 248 · 30510.1016/0022-0728(88)85092-7 ↗
37. Kulesza P. J. · J. Electroanal. Chem. Interfacial Electrochem. · 1989 · 259 · 8110.1016/0022-0728(89)80040-3 ↗
38. Kulesza P. J. · J. Electroanal. Chem. · 1992 · 336 · 3510.1016/0022-0728(92)80260-B ↗
39. Sadakane M. · Chem. Rev. · 1998 · 98 · 21910.1021/cr960403a ↗
40. Rand D. A. J. · J. Electroanal. Chem. Interfacial Electrochem. · 1972 · 35 · 20910.1016/S0022-0728(72)80308-5 ↗
41. Téazéa A. · 1990 · 8510.1002/9780470132586.ch16 ↗
42. Savinov E. N. · React. Kinet. Catal. Lett. · 1981 · 17 · 40710.1007/BF02065856 ↗
43. Rausch B. · Science · 2014 · 345 · 132610.1126/science.1257443 ↗
44. Bockris J. O. · J. Electrochem. Soc. · 1952 · 99 · 16910.1149/1.2779692 ↗
45. Climent V. · J. Solid State Electrochem. · 2011 · 15 · 129710.1007/s10008-011-1372-1 ↗
46. Angerstein-Kozlowska H. · J. Electroanal. Chem. Interfacial Electrochem. · 1973 · 43 · 910.1016/S0022-0728(73)80307-9 ↗
47. Jun W. · Chem. J. Chin. Univ. · 1992 · 13 · 1428
48. Liu Z. · Langmuir · 2002 · 18 · 405410.1021/la0116903 ↗
49. Moulder J. F. · 1995
50. Dückers K. · Surf. Sci. · 1986 · 166 · 14110.1016/0039-6028(86)90537-6 ↗
51. Romeo M. · Surf. Sci. · 1990 · 238 · 16310.1016/0039-6028(90)90073-H ↗