journal article·2017-03-08

Combined High Stretchability and Gas Barrier in Hydrogen-Bonded Multilayer Nanobrick Wall Thin Films

Shuang Qin, Yixuan Song, Michael E. Floto, Jaime C. Grunlan

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Abstract

Hydrogen-bonded multilayer thin films are very stretchable, but their gas barrier properties are modest compared to more traditional ionically bonded assemblies. In an effort to improve the gas barrier of poly(ethylene oxide) (PEO)-poly(acrylic acid) (PAA) multilayer films without sacrificing stretchability, montmorillonite (MMT) clay platelets were combined with PAA and alternately deposited with PEO. A ten-bilayer PEO/PAA+MMT film (432 nm thick), deposited on a 1 mm PU substrate, resulted in a 54× reduction in oxygen transmission rate after exposure to a 20% strain. This system is the best combination of stretchability and gas barrier ever reported.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Polymer Surface Interaction Studies · Metal and Thin Film Mechanics · Molecular Junctions and Nanostructures

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, ‡Department of Chemistry, and §Department of Mechanical Engineering, Texas A&M University, College Station, Texas 77843, United States

Funding

Division of Chemical, Bioengineering, Environmental, and Transport Systems

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