Surface Functionalization of Metal–Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance
Source abstract
Abstract
Robust catechol coatings for enhanced moisture tolerance were produced in one step by direct reaction of Hong Kong University of Science and Technology (HKUST) with synthetic catechols. We ascribe the rapid formation of homogeneous coatings around the metal-organic framework particles to the biomimetic catalytic activity of Cu(II) dimers in the external surface of the crystals. Use of fluorinated catechols results in hydrophobic, permeable coatings that protect HKUST from water degradation while retaining close to 100% of its original sorption capacity.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · X-ray Diffraction in Crystallography · Covalent Organic Framework Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Instituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán-2 46980, Paterna, Spain
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB 08193, Bellaterra, Spain
Funding
Generalitat Valenciana · Consejer?a de Econom?a, Innovaci?n, Ciencia y Empleo, Junta de Andaluc?a · European Regional Development Fund · Ministerio de Econom?a y Competitividad · H2020 European Research Council
References (42)
Show source-provided references
1. 10.1126/science.123044410.1126/science.1230444 ↗
2. 10.1038/nature1743010.1038/nature17430 ↗
3. 10.1038/nature1573210.1038/nature15732 ↗
4. 10.1126/science.aaf632310.1126/science.aaf6323 ↗
5. 10.1038/ncomms1183110.1038/ncomms11831 ↗
6. 10.1038/nature1976310.1038/nature19763 ↗
7. 10.1038/nmat423810.1038/nmat4238 ↗
8. 10.1002/anie.20150209410.1002/anie.201502094 ↗
9. 10.1002/chem.20120121210.1002/chem.201201212 ↗
10. 10.1021/ja906134410.1021/ja9061344 ↗
11. 10.1021/ja512382f10.1021/ja512382f ↗
12. 10.1002/anie.20140430610.1002/anie.201404306 ↗
13. 10.1021/ja208408n10.1021/ja208408n ↗
14. 10.1073/pnas.060243910310.1073/pnas.0602439103 ↗
15. 10.1039/c1sc00136a10.1039/c1sc00136a ↗
16. 10.1021/jacs.5b1088110.1021/jacs.5b10881 ↗
17. 10.1021/ja805795310.1021/ja8057953 ↗
18. 10.1002/anie.20120447510.1002/anie.201204475 ↗
19. 10.1002/anie.20120480610.1002/anie.201204806 ↗
20. 10.1039/C4CS00081A10.1039/C4CS00081A ↗
21. 10.1021/ja211182m10.1021/ja211182m ↗
22. 10.1021/ja100900c10.1021/ja100900c ↗
23. 10.1002/adma.20120079010.1002/adma.201200790 ↗
24. 10.1021/ja509960n10.1021/ja509960n ↗
25. 10.1002/adma.20140382710.1002/adma.201403827 ↗
26. 10.1002/adma.20120438310.1002/adma.201204383 ↗
27. 10.1002/adma.20150498210.1002/adma.201504982 ↗
28. 10.1039/C5NR05190H10.1039/C5NR05190H ↗
29. 10.1039/C6DT02032A10.1039/C6DT02032A ↗
30. 10.1039/b516250p10.1039/b516250p ↗
31. 10.1039/C4CS00185K10.1039/C4CS00185K ↗
32. 10.1126/science.283.5405.114810.1126/science.283.5405.1148 ↗
33. 10.1016/j.micromeso.2013.06.03310.1016/j.micromeso.2013.06.033 ↗
34. 10.1016/j.micromeso.2008.11.02010.1016/j.micromeso.2008.11.020 ↗
35. 10.1021/la00024a03710.1021/la00024a037 ↗
36. 10.1021/jp401367k10.1021/jp401367k ↗
37. 10.1016/j.apsusc.2010.07.08610.1016/j.apsusc.2010.07.086 ↗
38. 10.1021/ja806974310.1021/ja8069743 ↗
39. 10.1002/anie.20100106310.1002/anie.201001063 ↗
40. 10.1021/bm025707n10.1021/bm025707n ↗
41. 10.1039/C4RA00850B10.1039/C4RA00850B ↗
42. 10.1002/chem.20110194010.1002/chem.201101940 ↗