journal article·2016-09-14

MOF-Derived Tungstated Zirconia as Strong Solid Acids toward High Catalytic Performance for Acetalization

Peng Wang, Jian Feng, Yupei Zhao, Shaobin Wang, Jian Liu

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Abstract

A strong solid acid, tungstated zirconia (WZ), has been prepared first using tungstate immobilized UiO-66 as precursors through a "double-solvent" impregnation method under mild calcination temperature. With moderate W contents, the as-synthesized WZ catalysts possess a high density of acid sites, and the proper heat treatment also has facilely led to a bunch of oligomeric tungsten clusters on stabilized tetragonal ZrO2. The resultant solid acids show an improved catalytic performance toward the benzaldehyde's acetalization in comparison with traditional zirconium hydroxide-prepared WZ. Notably, due to large surface area and additionally introduced strong acid sites, the MOF-derived WZ catalysts afforded conversion up to 86.0%. The facile method endows the WZ catalysts with superior catalytic activities and excellent recyclability, thus opening a new avenue for preparation of metal oxide-based solid superacids and superbases.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Chemical Synthesis and Reactions · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Gehu Road 1, Changzhou, Jiangsu 213164, People’s Republic of China

Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Gehu Road 1, Changzhou, Jiangsu 213164, People’s Republic of China

Department of Chemical Engineering, Curtin University, P. O. Box U1987, Perth, Western Australia 6845, Australia

Nanochemistry Research Institute, Curtin University, P. O. Box U1987, Perth, Western Australia 6845, Australia

Funding

Natural Science Foundation of Jiangsu Province · National Natural Science Foundation of China · Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University · Priority Academic Program Development of Jiangsu Higher Education Institutions

References (52)

Show source-provided references
1. 10.2174/13852721179807243010.2174/138527211798072430 ↗
2. 10.1038/nchem.43310.1038/nchem.433 ↗
3. 10.1002/cssc.20130041610.1002/cssc.201300416 ↗
4. 10.1016/j.jcat.2016.05.00110.1016/j.jcat.2016.05.001 ↗
5. 10.1006/jcat.2001.342610.1006/jcat.2001.3426 ↗
6. 10.1021/cr900392410.1021/cr9003924 ↗
7. 10.1039/C5EE00762C10.1039/C5EE00762C ↗
8. 10.1039/C4TA04277H10.1039/C4TA04277H ↗
9. 10.1002/smll.20130291010.1002/smll.201302910 ↗
10. 10.1021/ja511539a10.1021/ja511539a ↗
11. 10.1039/C5CE00960J10.1039/C5CE00960J ↗
12. 10.1039/C4RA14728F10.1039/C4RA14728F ↗
13. 10.1021/ja805795310.1021/ja8057953 ↗
14. 10.1021/ja405078u10.1021/ja405078u ↗
15. 10.1039/C5SC04953A10.1039/C5SC04953A ↗
16. 10.1016/j.jcat.2004.03.02310.1016/j.jcat.2004.03.023 ↗
17. 10.1021/ja507119n10.1021/ja507119n ↗
18. 10.1021/cm035353m10.1021/cm035353m ↗
19. 10.1021/ja304390510.1021/ja3043905 ↗
20. 10.1039/C5CS00837A10.1039/C5CS00837A ↗
21. 10.1039/C5GC02615F10.1039/C5GC02615F ↗
22. 10.1039/c3cc39275a10.1039/c3cc39275a ↗
23. 10.1039/C5CC07042B10.1039/C5CC07042B ↗
24. 10.1016/j.micromeso.2012.08.00310.1016/j.micromeso.2012.08.003 ↗
25. 10.1016/j.cej.2011.09.01010.1016/j.cej.2011.09.010 ↗
26. 10.1021/acs.chemrev.5b0073110.1021/acs.chemrev.5b00731 ↗
27. 10.1039/C4TA04230A10.1039/C4TA04230A ↗
28. 10.1002/cssc.20120038310.1002/cssc.201200383 ↗
29. 10.1016/j.apcata.2004.04.01310.1016/j.apcata.2004.04.013 ↗
30. 10.1021/jp053255d10.1021/jp053255d ↗
31. 10.1021/la020223y10.1021/la020223y ↗
32. 10.1021/jp048435m10.1021/jp048435m ↗
33. 10.1021/jp983555d10.1021/jp983555d ↗
34. 10.1016/j.jcat.2004.08.01410.1016/j.jcat.2004.08.014 ↗
35. 10.1021/jp022313h10.1021/jp022313h ↗
36. 10.1016/j.jcat.2008.02.02610.1016/j.jcat.2008.02.026 ↗
37. 10.1016/j.jcat.2004.05.00610.1016/j.jcat.2004.05.006 ↗
38. 10.1016/S0926-860X(02)00523-910.1016/S0926-860X(02)00523-9 ↗
39. 10.1006/jcat.1998.226910.1006/jcat.1998.2269 ↗
40. 10.1021/la980222z10.1021/la980222z ↗
41. 10.1021/jp710409g10.1021/jp710409g ↗
42. 10.1021/jp057122410.1021/jp0571224 ↗
43. 10.1016/S0926-860X(97)00176-210.1016/S0926-860X(97)00176-2 ↗
44. 10.1021/la971399g10.1021/la971399g ↗
45. 10.1021/jp074219c10.1021/jp074219c ↗
46. 10.1016/j.cattod.2010.06.00210.1016/j.cattod.2010.06.002 ↗
47. 10.1021/jp990638110.1021/jp9906381 ↗
48. 10.1006/jcat.2000.315110.1006/jcat.2000.3151 ↗
49. 10.1023/A:101905022889410.1023/A:1019050228894 ↗
50. 10.1006/jcat.1997.176110.1006/jcat.1997.1761 ↗
51. 10.1021/cm501216c10.1021/cm501216c ↗
52. 10.1039/c2jm32261g10.1039/c2jm32261g ↗